Cargando…

catena-Poly[[[bis­(4-ethyl­benzoato-κ(2) O,O′)lead(II)]-μ-nicotinamide-κ(2) N (1):O] monohydrate]

In the crystal structure of the polymeric title compound, {[Pb(C(9)H(9)O(2))(2)(C(6)H(6)N(2)O)]·H(2)O}(n), the six-coordinate Pb(II) ion is chelated by two 4-ethyl­benzoate (PEB) anions and is bridged by two nicotinamide (NA) ligands, forming a polymeric chain running along the b axis. The carboxyl­...

Descripción completa

Detalles Bibliográficos
Autores principales: Hökelek, Tuncer, Tercan, Barış, Şahin, Ertan, Aktaş, Vedat, Necefoğlu, Hacali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212141/
https://www.ncbi.nlm.nih.gov/pubmed/22090843
http://dx.doi.org/10.1107/S1600536811026535
_version_ 1782215927731847168
author Hökelek, Tuncer
Tercan, Barış
Şahin, Ertan
Aktaş, Vedat
Necefoğlu, Hacali
author_facet Hökelek, Tuncer
Tercan, Barış
Şahin, Ertan
Aktaş, Vedat
Necefoğlu, Hacali
author_sort Hökelek, Tuncer
collection PubMed
description In the crystal structure of the polymeric title compound, {[Pb(C(9)H(9)O(2))(2)(C(6)H(6)N(2)O)]·H(2)O}(n), the six-coordinate Pb(II) ion is chelated by two 4-ethyl­benzoate (PEB) anions and is bridged by two nicotinamide (NA) ligands, forming a polymeric chain running along the b axis. The carboxyl­ate groups of the PEB ions are twisted away from the attached benzene rings by 4.0 (6) and 13.3 (5)°. The two benzene rings of the PEB ions bonded to the same metal ion are oriented at a dihedral angle of 87.4 (3)°. In the polymeric chain, the NA ligand is linked to one of the carboxyl­ate groups via N—H⋯O hydrogen bonding. In the crystal, adjacent polymeric chains inter­act via N—H⋯O and weak C—H⋯O hydrogen bonds; and the lattice water mol­ecule links with the polymeric chains via N—H⋯O and O—H⋯O hydrogen bonding. π–π stacking between the benzene and the pyridine rings [centroid–centroid distance = 3.805 (5) Å] and weak C—H⋯π inter­actions are also observed in the crystal structure.
format Online
Article
Text
id pubmed-3212141
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32121412011-11-16 catena-Poly[[[bis­(4-ethyl­benzoato-κ(2) O,O′)lead(II)]-μ-nicotinamide-κ(2) N (1):O] monohydrate] Hökelek, Tuncer Tercan, Barış Şahin, Ertan Aktaş, Vedat Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the polymeric title compound, {[Pb(C(9)H(9)O(2))(2)(C(6)H(6)N(2)O)]·H(2)O}(n), the six-coordinate Pb(II) ion is chelated by two 4-ethyl­benzoate (PEB) anions and is bridged by two nicotinamide (NA) ligands, forming a polymeric chain running along the b axis. The carboxyl­ate groups of the PEB ions are twisted away from the attached benzene rings by 4.0 (6) and 13.3 (5)°. The two benzene rings of the PEB ions bonded to the same metal ion are oriented at a dihedral angle of 87.4 (3)°. In the polymeric chain, the NA ligand is linked to one of the carboxyl­ate groups via N—H⋯O hydrogen bonding. In the crystal, adjacent polymeric chains inter­act via N—H⋯O and weak C—H⋯O hydrogen bonds; and the lattice water mol­ecule links with the polymeric chains via N—H⋯O and O—H⋯O hydrogen bonding. π–π stacking between the benzene and the pyridine rings [centroid–centroid distance = 3.805 (5) Å] and weak C—H⋯π inter­actions are also observed in the crystal structure. International Union of Crystallography 2011-07-09 /pmc/articles/PMC3212141/ /pubmed/22090843 http://dx.doi.org/10.1107/S1600536811026535 Text en © Hökelek et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hökelek, Tuncer
Tercan, Barış
Şahin, Ertan
Aktaş, Vedat
Necefoğlu, Hacali
catena-Poly[[[bis­(4-ethyl­benzoato-κ(2) O,O′)lead(II)]-μ-nicotinamide-κ(2) N (1):O] monohydrate]
title catena-Poly[[[bis­(4-ethyl­benzoato-κ(2) O,O′)lead(II)]-μ-nicotinamide-κ(2) N (1):O] monohydrate]
title_full catena-Poly[[[bis­(4-ethyl­benzoato-κ(2) O,O′)lead(II)]-μ-nicotinamide-κ(2) N (1):O] monohydrate]
title_fullStr catena-Poly[[[bis­(4-ethyl­benzoato-κ(2) O,O′)lead(II)]-μ-nicotinamide-κ(2) N (1):O] monohydrate]
title_full_unstemmed catena-Poly[[[bis­(4-ethyl­benzoato-κ(2) O,O′)lead(II)]-μ-nicotinamide-κ(2) N (1):O] monohydrate]
title_short catena-Poly[[[bis­(4-ethyl­benzoato-κ(2) O,O′)lead(II)]-μ-nicotinamide-κ(2) N (1):O] monohydrate]
title_sort catena-poly[[[bis­(4-ethyl­benzoato-κ(2) o,o′)lead(ii)]-μ-nicotinamide-κ(2) n (1):o] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212141/
https://www.ncbi.nlm.nih.gov/pubmed/22090843
http://dx.doi.org/10.1107/S1600536811026535
work_keys_str_mv AT hokelektuncer catenapolybis4ethylbenzoatok2ooleadiimnicotinamidek2n1omonohydrate
AT tercanbarıs catenapolybis4ethylbenzoatok2ooleadiimnicotinamidek2n1omonohydrate
AT sahinertan catenapolybis4ethylbenzoatok2ooleadiimnicotinamidek2n1omonohydrate
AT aktasvedat catenapolybis4ethylbenzoatok2ooleadiimnicotinamidek2n1omonohydrate
AT necefogluhacali catenapolybis4ethylbenzoatok2ooleadiimnicotinamidek2n1omonohydrate