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catena-Poly[[[bis(4-ethylbenzoato-κ(2) O,O′)lead(II)]-μ-nicotinamide-κ(2) N (1):O] monohydrate]
In the crystal structure of the polymeric title compound, {[Pb(C(9)H(9)O(2))(2)(C(6)H(6)N(2)O)]·H(2)O}(n), the six-coordinate Pb(II) ion is chelated by two 4-ethylbenzoate (PEB) anions and is bridged by two nicotinamide (NA) ligands, forming a polymeric chain running along the b axis. The carboxyl...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212141/ https://www.ncbi.nlm.nih.gov/pubmed/22090843 http://dx.doi.org/10.1107/S1600536811026535 |
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author | Hökelek, Tuncer Tercan, Barış Şahin, Ertan Aktaş, Vedat Necefoğlu, Hacali |
author_facet | Hökelek, Tuncer Tercan, Barış Şahin, Ertan Aktaş, Vedat Necefoğlu, Hacali |
author_sort | Hökelek, Tuncer |
collection | PubMed |
description | In the crystal structure of the polymeric title compound, {[Pb(C(9)H(9)O(2))(2)(C(6)H(6)N(2)O)]·H(2)O}(n), the six-coordinate Pb(II) ion is chelated by two 4-ethylbenzoate (PEB) anions and is bridged by two nicotinamide (NA) ligands, forming a polymeric chain running along the b axis. The carboxylate groups of the PEB ions are twisted away from the attached benzene rings by 4.0 (6) and 13.3 (5)°. The two benzene rings of the PEB ions bonded to the same metal ion are oriented at a dihedral angle of 87.4 (3)°. In the polymeric chain, the NA ligand is linked to one of the carboxylate groups via N—H⋯O hydrogen bonding. In the crystal, adjacent polymeric chains interact via N—H⋯O and weak C—H⋯O hydrogen bonds; and the lattice water molecule links with the polymeric chains via N—H⋯O and O—H⋯O hydrogen bonding. π–π stacking between the benzene and the pyridine rings [centroid–centroid distance = 3.805 (5) Å] and weak C—H⋯π interactions are also observed in the crystal structure. |
format | Online Article Text |
id | pubmed-3212141 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32121412011-11-16 catena-Poly[[[bis(4-ethylbenzoato-κ(2) O,O′)lead(II)]-μ-nicotinamide-κ(2) N (1):O] monohydrate] Hökelek, Tuncer Tercan, Barış Şahin, Ertan Aktaş, Vedat Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the polymeric title compound, {[Pb(C(9)H(9)O(2))(2)(C(6)H(6)N(2)O)]·H(2)O}(n), the six-coordinate Pb(II) ion is chelated by two 4-ethylbenzoate (PEB) anions and is bridged by two nicotinamide (NA) ligands, forming a polymeric chain running along the b axis. The carboxylate groups of the PEB ions are twisted away from the attached benzene rings by 4.0 (6) and 13.3 (5)°. The two benzene rings of the PEB ions bonded to the same metal ion are oriented at a dihedral angle of 87.4 (3)°. In the polymeric chain, the NA ligand is linked to one of the carboxylate groups via N—H⋯O hydrogen bonding. In the crystal, adjacent polymeric chains interact via N—H⋯O and weak C—H⋯O hydrogen bonds; and the lattice water molecule links with the polymeric chains via N—H⋯O and O—H⋯O hydrogen bonding. π–π stacking between the benzene and the pyridine rings [centroid–centroid distance = 3.805 (5) Å] and weak C—H⋯π interactions are also observed in the crystal structure. International Union of Crystallography 2011-07-09 /pmc/articles/PMC3212141/ /pubmed/22090843 http://dx.doi.org/10.1107/S1600536811026535 Text en © Hökelek et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hökelek, Tuncer Tercan, Barış Şahin, Ertan Aktaş, Vedat Necefoğlu, Hacali catena-Poly[[[bis(4-ethylbenzoato-κ(2) O,O′)lead(II)]-μ-nicotinamide-κ(2) N (1):O] monohydrate] |
title |
catena-Poly[[[bis(4-ethylbenzoato-κ(2)
O,O′)lead(II)]-μ-nicotinamide-κ(2)
N
(1):O] monohydrate] |
title_full |
catena-Poly[[[bis(4-ethylbenzoato-κ(2)
O,O′)lead(II)]-μ-nicotinamide-κ(2)
N
(1):O] monohydrate] |
title_fullStr |
catena-Poly[[[bis(4-ethylbenzoato-κ(2)
O,O′)lead(II)]-μ-nicotinamide-κ(2)
N
(1):O] monohydrate] |
title_full_unstemmed |
catena-Poly[[[bis(4-ethylbenzoato-κ(2)
O,O′)lead(II)]-μ-nicotinamide-κ(2)
N
(1):O] monohydrate] |
title_short |
catena-Poly[[[bis(4-ethylbenzoato-κ(2)
O,O′)lead(II)]-μ-nicotinamide-κ(2)
N
(1):O] monohydrate] |
title_sort | catena-poly[[[bis(4-ethylbenzoato-κ(2)
o,o′)lead(ii)]-μ-nicotinamide-κ(2)
n
(1):o] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212141/ https://www.ncbi.nlm.nih.gov/pubmed/22090843 http://dx.doi.org/10.1107/S1600536811026535 |
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