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Bis[2,6-bis(3,5-dimethyl-1H-pyrazol-1-yl)pyridine]di-μ(3)-iodido-diiodidotetracopper(I)
In the title centrosymmetric tetranuclear complex, [Cu(4)I(4)(C(15)H(17)N(5))(2)], the two distinct Cu(I) atoms adopt similar tetrahedral arrangements, each being ligated by two I atoms, and two N atoms from one 2,6-bis(3,5-dimethyl-1H-pyrazol-1-yl)pyridine ligand. In the crystal, there are no hy...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212142/ https://www.ncbi.nlm.nih.gov/pubmed/22090844 http://dx.doi.org/10.1107/S1600536811026468 |
| _version_ | 1782215927948902400 |
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| author | Jia, Chun-Xiao |
| author_facet | Jia, Chun-Xiao |
| author_sort | Jia, Chun-Xiao |
| collection | PubMed |
| description | In the title centrosymmetric tetranuclear complex, [Cu(4)I(4)(C(15)H(17)N(5))(2)], the two distinct Cu(I) atoms adopt similar tetrahedral arrangements, each being ligated by two I atoms, and two N atoms from one 2,6-bis(3,5-dimethyl-1H-pyrazol-1-yl)pyridine ligand. In the crystal, there are no hydrogen bonds present, and only very weak π–π interactions are observed [centroid–centroid distance = 3.985 (4) Å], which connect neighbouring tetranuclear units into a chain motif along the b axis. |
| format | Online Article Text |
| id | pubmed-3212142 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32121422011-11-16 Bis[2,6-bis(3,5-dimethyl-1H-pyrazol-1-yl)pyridine]di-μ(3)-iodido-diiodidotetracopper(I) Jia, Chun-Xiao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title centrosymmetric tetranuclear complex, [Cu(4)I(4)(C(15)H(17)N(5))(2)], the two distinct Cu(I) atoms adopt similar tetrahedral arrangements, each being ligated by two I atoms, and two N atoms from one 2,6-bis(3,5-dimethyl-1H-pyrazol-1-yl)pyridine ligand. In the crystal, there are no hydrogen bonds present, and only very weak π–π interactions are observed [centroid–centroid distance = 3.985 (4) Å], which connect neighbouring tetranuclear units into a chain motif along the b axis. International Union of Crystallography 2011-07-09 /pmc/articles/PMC3212142/ /pubmed/22090844 http://dx.doi.org/10.1107/S1600536811026468 Text en © Chun-Xiao Jia 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Jia, Chun-Xiao Bis[2,6-bis(3,5-dimethyl-1H-pyrazol-1-yl)pyridine]di-μ(3)-iodido-diiodidotetracopper(I) |
| title | Bis[2,6-bis(3,5-dimethyl-1H-pyrazol-1-yl)pyridine]di-μ(3)-iodido-diiodidotetracopper(I) |
| title_full | Bis[2,6-bis(3,5-dimethyl-1H-pyrazol-1-yl)pyridine]di-μ(3)-iodido-diiodidotetracopper(I) |
| title_fullStr | Bis[2,6-bis(3,5-dimethyl-1H-pyrazol-1-yl)pyridine]di-μ(3)-iodido-diiodidotetracopper(I) |
| title_full_unstemmed | Bis[2,6-bis(3,5-dimethyl-1H-pyrazol-1-yl)pyridine]di-μ(3)-iodido-diiodidotetracopper(I) |
| title_short | Bis[2,6-bis(3,5-dimethyl-1H-pyrazol-1-yl)pyridine]di-μ(3)-iodido-diiodidotetracopper(I) |
| title_sort | bis[2,6-bis(3,5-dimethyl-1h-pyrazol-1-yl)pyridine]di-μ(3)-iodido-diiodidotetracopper(i) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212142/ https://www.ncbi.nlm.nih.gov/pubmed/22090844 http://dx.doi.org/10.1107/S1600536811026468 |
| work_keys_str_mv | AT jiachunxiao bis26bis35dimethyl1hpyrazol1ylpyridinedim3iodidodiiodidotetracopperi |