[2-(1H-Benzimidazol-2-yl-κN (3))aniline-κN]dichloridozinc

In the title benzimidazole mononuclear complex, [ZnCl(2)(C(13)H(11)N(3))], the Zn(II) ion is four-coordinated in a distorted tetra­hedral geometry by an imidazole N, an amino N and two Cl atoms. The dihedral angle between the benzimidazole and benzene rings is 9.57 (1)°. In the crystal, mol­ecules a...

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Detalles Bibliográficos
Autores principales: Eltayeb, Naser Eltaher, Teoh, Siang Guan, Chantrapromma, Suchada, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212144/
https://www.ncbi.nlm.nih.gov/pubmed/22090846
http://dx.doi.org/10.1107/S1600536811026572
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author Eltayeb, Naser Eltaher
Teoh, Siang Guan
Chantrapromma, Suchada
Fun, Hoong-Kun
author_facet Eltayeb, Naser Eltaher
Teoh, Siang Guan
Chantrapromma, Suchada
Fun, Hoong-Kun
author_sort Eltayeb, Naser Eltaher
collection PubMed
description In the title benzimidazole mononuclear complex, [ZnCl(2)(C(13)H(11)N(3))], the Zn(II) ion is four-coordinated in a distorted tetra­hedral geometry by an imidazole N, an amino N and two Cl atoms. The dihedral angle between the benzimidazole and benzene rings is 9.57 (1)°. In the crystal, mol­ecules are linked by weak N—H⋯Cl hydrogen bonds into layers parallel to the bc plane. π–π inter­actions with centroid–centroid distances in the range 3.4452 (8)–3.8074 (8) Å are also observed.
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spelling pubmed-32121442011-11-16 [2-(1H-Benzimidazol-2-yl-κN (3))aniline-κN]dichloridozinc Eltayeb, Naser Eltaher Teoh, Siang Guan Chantrapromma, Suchada Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title benzimidazole mononuclear complex, [ZnCl(2)(C(13)H(11)N(3))], the Zn(II) ion is four-coordinated in a distorted tetra­hedral geometry by an imidazole N, an amino N and two Cl atoms. The dihedral angle between the benzimidazole and benzene rings is 9.57 (1)°. In the crystal, mol­ecules are linked by weak N—H⋯Cl hydrogen bonds into layers parallel to the bc plane. π–π inter­actions with centroid–centroid distances in the range 3.4452 (8)–3.8074 (8) Å are also observed. International Union of Crystallography 2011-07-09 /pmc/articles/PMC3212144/ /pubmed/22090846 http://dx.doi.org/10.1107/S1600536811026572 Text en © Eltayeb et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Eltayeb, Naser Eltaher
Teoh, Siang Guan
Chantrapromma, Suchada
Fun, Hoong-Kun
[2-(1H-Benzimidazol-2-yl-κN (3))aniline-κN]dichloridozinc
title [2-(1H-Benzimidazol-2-yl-κN (3))aniline-κN]dichloridozinc
title_full [2-(1H-Benzimidazol-2-yl-κN (3))aniline-κN]dichloridozinc
title_fullStr [2-(1H-Benzimidazol-2-yl-κN (3))aniline-κN]dichloridozinc
title_full_unstemmed [2-(1H-Benzimidazol-2-yl-κN (3))aniline-κN]dichloridozinc
title_short [2-(1H-Benzimidazol-2-yl-κN (3))aniline-κN]dichloridozinc
title_sort [2-(1h-benzimidazol-2-yl-κn (3))aniline-κn]dichloridozinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212144/
https://www.ncbi.nlm.nih.gov/pubmed/22090846
http://dx.doi.org/10.1107/S1600536811026572
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AT chantraprommasuchada 21hbenzimidazol2ylkn3anilinekndichloridozinc
AT funhoongkun 21hbenzimidazol2ylkn3anilinekndichloridozinc

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