Bis(O-n-butyl dithio­carbonato-κ(2) S,S′)bis­(pyridine-κN)manganese(II)

The structure of the title manganese complex, [Mn(C(5)H(9)OS(2))(2)(C(5)H(5)N)(2)] or [Mn(S(2)CO-n-Bu)(2)(C(5)H(5)N)(2)], consists of discrete monomeric entities with Mn(2+) ions located on centres of inversion. The metal atom is coordinated by a six-coordinate trans-N(2)S(4) donor set with the pyri...

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Autores principales: Alam, Naveed, Ehsan, Muhammad Ali, Zeller, Matthias, Mazhar, Muhammad, Arifin, Zainudin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212145/
https://www.ncbi.nlm.nih.gov/pubmed/22090847
http://dx.doi.org/10.1107/S1600536811026523
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author Alam, Naveed
Ehsan, Muhammad Ali
Zeller, Matthias
Mazhar, Muhammad
Arifin, Zainudin
author_facet Alam, Naveed
Ehsan, Muhammad Ali
Zeller, Matthias
Mazhar, Muhammad
Arifin, Zainudin
author_sort Alam, Naveed
collection PubMed
description The structure of the title manganese complex, [Mn(C(5)H(9)OS(2))(2)(C(5)H(5)N)(2)] or [Mn(S(2)CO-n-Bu)(2)(C(5)H(5)N)(2)], consists of discrete monomeric entities with Mn(2+) ions located on centres of inversion. The metal atom is coordinated by a six-coordinate trans-N(2)S(4) donor set with the pyridyl N atoms located in the apical positions. The observed slight deviations from octa­hedral geometry are caused by the bite angle of the bidentate κ(2)-S(2)CO-n-Bu ligands [69.48 (1)°]. The O(CH(2))(3)(CH(3)) chains of the O-n-butyl dithio­carbonate units are disordered over two sets of sites with an occupancy ratio of 0.589 (2):0.411 (2).
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spelling pubmed-32121452011-11-16 Bis(O-n-butyl dithio­carbonato-κ(2) S,S′)bis­(pyridine-κN)manganese(II) Alam, Naveed Ehsan, Muhammad Ali Zeller, Matthias Mazhar, Muhammad Arifin, Zainudin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title manganese complex, [Mn(C(5)H(9)OS(2))(2)(C(5)H(5)N)(2)] or [Mn(S(2)CO-n-Bu)(2)(C(5)H(5)N)(2)], consists of discrete monomeric entities with Mn(2+) ions located on centres of inversion. The metal atom is coordinated by a six-coordinate trans-N(2)S(4) donor set with the pyridyl N atoms located in the apical positions. The observed slight deviations from octa­hedral geometry are caused by the bite angle of the bidentate κ(2)-S(2)CO-n-Bu ligands [69.48 (1)°]. The O(CH(2))(3)(CH(3)) chains of the O-n-butyl dithio­carbonate units are disordered over two sets of sites with an occupancy ratio of 0.589 (2):0.411 (2). International Union of Crystallography 2011-07-09 /pmc/articles/PMC3212145/ /pubmed/22090847 http://dx.doi.org/10.1107/S1600536811026523 Text en © Alam et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Alam, Naveed
Ehsan, Muhammad Ali
Zeller, Matthias
Mazhar, Muhammad
Arifin, Zainudin
Bis(O-n-butyl dithio­carbonato-κ(2) S,S′)bis­(pyridine-κN)manganese(II)
title Bis(O-n-butyl dithio­carbonato-κ(2) S,S′)bis­(pyridine-κN)manganese(II)
title_full Bis(O-n-butyl dithio­carbonato-κ(2) S,S′)bis­(pyridine-κN)manganese(II)
title_fullStr Bis(O-n-butyl dithio­carbonato-κ(2) S,S′)bis­(pyridine-κN)manganese(II)
title_full_unstemmed Bis(O-n-butyl dithio­carbonato-κ(2) S,S′)bis­(pyridine-κN)manganese(II)
title_short Bis(O-n-butyl dithio­carbonato-κ(2) S,S′)bis­(pyridine-κN)manganese(II)
title_sort bis(o-n-butyl dithio­carbonato-κ(2) s,s′)bis­(pyridine-κn)manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212145/
https://www.ncbi.nlm.nih.gov/pubmed/22090847
http://dx.doi.org/10.1107/S1600536811026523
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