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catena-Poly[[diaquabis(3-methylpyridine-κN)cobalt(II)]-μ-sulfato-κ(2) O:O′]
The environment of the Co(II) ion in the title compound, [Co(SO(4))(C(6)H(7)N)(2)(H(2)O)(2)](n), exhibits an octahedral configuration with the two 3-methylpyridine ligands lying in cis positions with respect to each other and trans to the two coordinated water molecules. The axial positions are o...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212146/ https://www.ncbi.nlm.nih.gov/pubmed/22090848 http://dx.doi.org/10.1107/S1600536811025815 |
Sumario: | The environment of the Co(II) ion in the title compound, [Co(SO(4))(C(6)H(7)N)(2)(H(2)O)(2)](n), exhibits an octahedral configuration with the two 3-methylpyridine ligands lying in cis positions with respect to each other and trans to the two coordinated water molecules. The axial positions are occupied by O atoms of the sulfate ions. Co and S atoms occupy special positions (twofold axis, Wyckoff position 4c). Neighboring Co(II) ions are covalently connected with each other through the sulfate ions, thus creating infinite polymeric chains that run along the c axis. The water molecules are connected with neighboring sulfate ions through strong O—H⋯O hydrogen bonds. Intramolecular hydrogen bonds parallel to the propagation direction of the chains stabilize the polymeric chains, and intermolecular hydrogen bonds between chains connect neighboring chains with each other, thus leading to polymeric double chains. |
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