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catena-Poly[[diaquabis(3-methylpyridine-κN)cobalt(II)]-μ-sulfato-κ(2) O:O′]
The environment of the Co(II) ion in the title compound, [Co(SO(4))(C(6)H(7)N)(2)(H(2)O)(2)](n), exhibits an octahedral configuration with the two 3-methylpyridine ligands lying in cis positions with respect to each other and trans to the two coordinated water molecules. The axial positions are o...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212146/ https://www.ncbi.nlm.nih.gov/pubmed/22090848 http://dx.doi.org/10.1107/S1600536811025815 |
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author | Alam, Naveed Zeller, Matthias Ahmad Tajidi, Nur Syamimi Arifin, Zainudin Mazhar, Muhammad |
author_facet | Alam, Naveed Zeller, Matthias Ahmad Tajidi, Nur Syamimi Arifin, Zainudin Mazhar, Muhammad |
author_sort | Alam, Naveed |
collection | PubMed |
description | The environment of the Co(II) ion in the title compound, [Co(SO(4))(C(6)H(7)N)(2)(H(2)O)(2)](n), exhibits an octahedral configuration with the two 3-methylpyridine ligands lying in cis positions with respect to each other and trans to the two coordinated water molecules. The axial positions are occupied by O atoms of the sulfate ions. Co and S atoms occupy special positions (twofold axis, Wyckoff position 4c). Neighboring Co(II) ions are covalently connected with each other through the sulfate ions, thus creating infinite polymeric chains that run along the c axis. The water molecules are connected with neighboring sulfate ions through strong O—H⋯O hydrogen bonds. Intramolecular hydrogen bonds parallel to the propagation direction of the chains stabilize the polymeric chains, and intermolecular hydrogen bonds between chains connect neighboring chains with each other, thus leading to polymeric double chains. |
format | Online Article Text |
id | pubmed-3212146 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32121462011-11-16 catena-Poly[[diaquabis(3-methylpyridine-κN)cobalt(II)]-μ-sulfato-κ(2) O:O′] Alam, Naveed Zeller, Matthias Ahmad Tajidi, Nur Syamimi Arifin, Zainudin Mazhar, Muhammad Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The environment of the Co(II) ion in the title compound, [Co(SO(4))(C(6)H(7)N)(2)(H(2)O)(2)](n), exhibits an octahedral configuration with the two 3-methylpyridine ligands lying in cis positions with respect to each other and trans to the two coordinated water molecules. The axial positions are occupied by O atoms of the sulfate ions. Co and S atoms occupy special positions (twofold axis, Wyckoff position 4c). Neighboring Co(II) ions are covalently connected with each other through the sulfate ions, thus creating infinite polymeric chains that run along the c axis. The water molecules are connected with neighboring sulfate ions through strong O—H⋯O hydrogen bonds. Intramolecular hydrogen bonds parallel to the propagation direction of the chains stabilize the polymeric chains, and intermolecular hydrogen bonds between chains connect neighboring chains with each other, thus leading to polymeric double chains. International Union of Crystallography 2011-07-09 /pmc/articles/PMC3212146/ /pubmed/22090848 http://dx.doi.org/10.1107/S1600536811025815 Text en © Alam et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Alam, Naveed Zeller, Matthias Ahmad Tajidi, Nur Syamimi Arifin, Zainudin Mazhar, Muhammad catena-Poly[[diaquabis(3-methylpyridine-κN)cobalt(II)]-μ-sulfato-κ(2) O:O′] |
title |
catena-Poly[[diaquabis(3-methylpyridine-κN)cobalt(II)]-μ-sulfato-κ(2)
O:O′] |
title_full |
catena-Poly[[diaquabis(3-methylpyridine-κN)cobalt(II)]-μ-sulfato-κ(2)
O:O′] |
title_fullStr |
catena-Poly[[diaquabis(3-methylpyridine-κN)cobalt(II)]-μ-sulfato-κ(2)
O:O′] |
title_full_unstemmed |
catena-Poly[[diaquabis(3-methylpyridine-κN)cobalt(II)]-μ-sulfato-κ(2)
O:O′] |
title_short |
catena-Poly[[diaquabis(3-methylpyridine-κN)cobalt(II)]-μ-sulfato-κ(2)
O:O′] |
title_sort | catena-poly[[diaquabis(3-methylpyridine-κn)cobalt(ii)]-μ-sulfato-κ(2)
o:o′] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212146/ https://www.ncbi.nlm.nih.gov/pubmed/22090848 http://dx.doi.org/10.1107/S1600536811025815 |
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