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catena-Poly[[diaqua­bis­(3-methyl­pyridine-κN)cobalt(II)]-μ-sulfato-κ(2) O:O′]

The environment of the Co(II) ion in the title compound, [Co(SO(4))(C(6)H(7)N)(2)(H(2)O)(2)](n), exhibits an octa­hedral configuration with the two 3-methyl­pyridine ligands lying in cis positions with respect to each other and trans to the two coordinated water mol­ecules. The axial positions are o...

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Autores principales: Alam, Naveed, Zeller, Matthias, Ahmad Tajidi, Nur Syamimi, Arifin, Zainudin, Mazhar, Muhammad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212146/
https://www.ncbi.nlm.nih.gov/pubmed/22090848
http://dx.doi.org/10.1107/S1600536811025815
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author Alam, Naveed
Zeller, Matthias
Ahmad Tajidi, Nur Syamimi
Arifin, Zainudin
Mazhar, Muhammad
author_facet Alam, Naveed
Zeller, Matthias
Ahmad Tajidi, Nur Syamimi
Arifin, Zainudin
Mazhar, Muhammad
author_sort Alam, Naveed
collection PubMed
description The environment of the Co(II) ion in the title compound, [Co(SO(4))(C(6)H(7)N)(2)(H(2)O)(2)](n), exhibits an octa­hedral configuration with the two 3-methyl­pyridine ligands lying in cis positions with respect to each other and trans to the two coordinated water mol­ecules. The axial positions are occupied by O atoms of the sulfate ions. Co and S atoms occupy special positions (twofold axis, Wyckoff position 4c). Neighboring Co(II) ions are covalently connected with each other through the sulfate ions, thus creating infinite polymeric chains that run along the c axis. The water mol­ecules are connected with neighboring sulfate ions through strong O—H⋯O hydrogen bonds. Intra­molecular hydrogen bonds parallel to the propagation direction of the chains stabilize the polymeric chains, and inter­molecular hydrogen bonds between chains connect neighboring chains with each other, thus leading to polymeric double chains.
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spelling pubmed-32121462011-11-16 catena-Poly[[diaqua­bis­(3-methyl­pyridine-κN)cobalt(II)]-μ-sulfato-κ(2) O:O′] Alam, Naveed Zeller, Matthias Ahmad Tajidi, Nur Syamimi Arifin, Zainudin Mazhar, Muhammad Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The environment of the Co(II) ion in the title compound, [Co(SO(4))(C(6)H(7)N)(2)(H(2)O)(2)](n), exhibits an octa­hedral configuration with the two 3-methyl­pyridine ligands lying in cis positions with respect to each other and trans to the two coordinated water mol­ecules. The axial positions are occupied by O atoms of the sulfate ions. Co and S atoms occupy special positions (twofold axis, Wyckoff position 4c). Neighboring Co(II) ions are covalently connected with each other through the sulfate ions, thus creating infinite polymeric chains that run along the c axis. The water mol­ecules are connected with neighboring sulfate ions through strong O—H⋯O hydrogen bonds. Intra­molecular hydrogen bonds parallel to the propagation direction of the chains stabilize the polymeric chains, and inter­molecular hydrogen bonds between chains connect neighboring chains with each other, thus leading to polymeric double chains. International Union of Crystallography 2011-07-09 /pmc/articles/PMC3212146/ /pubmed/22090848 http://dx.doi.org/10.1107/S1600536811025815 Text en © Alam et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Alam, Naveed
Zeller, Matthias
Ahmad Tajidi, Nur Syamimi
Arifin, Zainudin
Mazhar, Muhammad
catena-Poly[[diaqua­bis­(3-methyl­pyridine-κN)cobalt(II)]-μ-sulfato-κ(2) O:O′]
title catena-Poly[[diaqua­bis­(3-methyl­pyridine-κN)cobalt(II)]-μ-sulfato-κ(2) O:O′]
title_full catena-Poly[[diaqua­bis­(3-methyl­pyridine-κN)cobalt(II)]-μ-sulfato-κ(2) O:O′]
title_fullStr catena-Poly[[diaqua­bis­(3-methyl­pyridine-κN)cobalt(II)]-μ-sulfato-κ(2) O:O′]
title_full_unstemmed catena-Poly[[diaqua­bis­(3-methyl­pyridine-κN)cobalt(II)]-μ-sulfato-κ(2) O:O′]
title_short catena-Poly[[diaqua­bis­(3-methyl­pyridine-κN)cobalt(II)]-μ-sulfato-κ(2) O:O′]
title_sort catena-poly[[diaqua­bis­(3-methyl­pyridine-κn)cobalt(ii)]-μ-sulfato-κ(2) o:o′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212146/
https://www.ncbi.nlm.nih.gov/pubmed/22090848
http://dx.doi.org/10.1107/S1600536811025815
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