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Dimeric (2-cyanophenolato-κO){2,2′-[ethylenebis(nitrilomethylidyne)]diphenolato-κ(4) O,N,N′,O′}manganese(III) monohydrate
The molecules of the title compound, [Mn(C(7)H(4)NO)(C(16)H(14)N(2)O(2))]·H(2)O, form dimers in the solid state across a crystallographic inversion center. The bridging Mn(2)O(2) group is built of phenoxy groups, and is asymmetric, with an Mn—O distances of 1.9002 (13) and 2.6236 (14) Å. A substant...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212148/ https://www.ncbi.nlm.nih.gov/pubmed/22090850 http://dx.doi.org/10.1107/S1600536811026584 |
| Sumario: | The molecules of the title compound, [Mn(C(7)H(4)NO)(C(16)H(14)N(2)O(2))]·H(2)O, form dimers in the solid state across a crystallographic inversion center. The bridging Mn(2)O(2) group is built of phenoxy groups, and is asymmetric, with an Mn—O distances of 1.9002 (13) and 2.6236 (14) Å. A substantial cavity between the two Mn atoms [Mn⋯Mn = 3.5082 (4) Å] is produced by the formation of the dimer. In the crystal, an extended network of O—H⋯O hydrogen-bonding interactions stabilizes the structure. |
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