Dimeric (2-cyano­phenolato-κO){2,2′-[ethyl­enebis(nitrilo­methyl­idyne)]diphenolato-κ(4) O,N,N′,O′}manganese(III) monohydrate

The molecules of the title compound, [Mn(C(7)H(4)NO)(C(16)H(14)N(2)O(2))]·H(2)O, form dimers in the solid state across a crystallographic inversion center. The bridging Mn(2)O(2) group is built of phen­oxy groups, and is asymmetric, with an Mn—O distances of 1.9002 (13) and 2.6236 (14) Å. A substant...

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Autores principales: Zidane, Youcef, Ourari, Ali, Mousser, Hénia, Mousser, Abdelhamid
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212148/
https://www.ncbi.nlm.nih.gov/pubmed/22090850
http://dx.doi.org/10.1107/S1600536811026584
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author Zidane, Youcef
Ourari, Ali
Mousser, Hénia
Mousser, Abdelhamid
author_facet Zidane, Youcef
Ourari, Ali
Mousser, Hénia
Mousser, Abdelhamid
author_sort Zidane, Youcef
collection PubMed
description The molecules of the title compound, [Mn(C(7)H(4)NO)(C(16)H(14)N(2)O(2))]·H(2)O, form dimers in the solid state across a crystallographic inversion center. The bridging Mn(2)O(2) group is built of phen­oxy groups, and is asymmetric, with an Mn—O distances of 1.9002 (13) and 2.6236 (14) Å. A substantial cavity between the two Mn atoms [Mn⋯Mn = 3.5082 (4) Å] is produced by the formation of the dimer. In the crystal, an extended network of O—H⋯O hydrogen-bonding inter­actions stabil­izes the structure.
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spelling pubmed-32121482011-11-16 Dimeric (2-cyano­phenolato-κO){2,2′-[ethyl­enebis(nitrilo­methyl­idyne)]diphenolato-κ(4) O,N,N′,O′}manganese(III) monohydrate Zidane, Youcef Ourari, Ali Mousser, Hénia Mousser, Abdelhamid Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The molecules of the title compound, [Mn(C(7)H(4)NO)(C(16)H(14)N(2)O(2))]·H(2)O, form dimers in the solid state across a crystallographic inversion center. The bridging Mn(2)O(2) group is built of phen­oxy groups, and is asymmetric, with an Mn—O distances of 1.9002 (13) and 2.6236 (14) Å. A substantial cavity between the two Mn atoms [Mn⋯Mn = 3.5082 (4) Å] is produced by the formation of the dimer. In the crystal, an extended network of O—H⋯O hydrogen-bonding inter­actions stabil­izes the structure. International Union of Crystallography 2011-07-09 /pmc/articles/PMC3212148/ /pubmed/22090850 http://dx.doi.org/10.1107/S1600536811026584 Text en © Zidane et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zidane, Youcef
Ourari, Ali
Mousser, Hénia
Mousser, Abdelhamid
Dimeric (2-cyano­phenolato-κO){2,2′-[ethyl­enebis(nitrilo­methyl­idyne)]diphenolato-κ(4) O,N,N′,O′}manganese(III) monohydrate
title Dimeric (2-cyano­phenolato-κO){2,2′-[ethyl­enebis(nitrilo­methyl­idyne)]diphenolato-κ(4) O,N,N′,O′}manganese(III) monohydrate
title_full Dimeric (2-cyano­phenolato-κO){2,2′-[ethyl­enebis(nitrilo­methyl­idyne)]diphenolato-κ(4) O,N,N′,O′}manganese(III) monohydrate
title_fullStr Dimeric (2-cyano­phenolato-κO){2,2′-[ethyl­enebis(nitrilo­methyl­idyne)]diphenolato-κ(4) O,N,N′,O′}manganese(III) monohydrate
title_full_unstemmed Dimeric (2-cyano­phenolato-κO){2,2′-[ethyl­enebis(nitrilo­methyl­idyne)]diphenolato-κ(4) O,N,N′,O′}manganese(III) monohydrate
title_short Dimeric (2-cyano­phenolato-κO){2,2′-[ethyl­enebis(nitrilo­methyl­idyne)]diphenolato-κ(4) O,N,N′,O′}manganese(III) monohydrate
title_sort dimeric (2-cyano­phenolato-κo){2,2′-[ethyl­enebis(nitrilo­methyl­idyne)]diphenolato-κ(4) o,n,n′,o′}manganese(iii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212148/
https://www.ncbi.nlm.nih.gov/pubmed/22090850
http://dx.doi.org/10.1107/S1600536811026584
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AT mousserhenia dimeric2cyanophenolatoko22ethylenebisnitrilomethylidynediphenolatok4onnomanganeseiiimonohydrate
AT mousserabdelhamid dimeric2cyanophenolatoko22ethylenebisnitrilomethylidynediphenolatok4onnomanganeseiiimonohydrate

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