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Tetra­aqua­bis­[4-(4H-1,2,4-triazol-4-yl)benzoato-κN (1)]manganese(II) deca­hydrate

In the title compound, [Mn(C(9)H(6)N(3)O(2))(2)(H(2)O)(4)]·10H(2)O, the Mn(II) ion is coordinated by two N atoms from two 4-(4H-1,2,4-triazol-4-yl)benzoate ligands and four water mol­ecules in a distorted octa­hedral geometry. The Mn(II) ion and two coordinated water mol­ecules lie on a twofold rota...

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Detalles Bibliográficos
Autores principales: Piao, Ying-Ai, Xuan, Zhen-Yu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212150/
https://www.ncbi.nlm.nih.gov/pubmed/22090852
http://dx.doi.org/10.1107/S1600536811025335
Descripción
Sumario:In the title compound, [Mn(C(9)H(6)N(3)O(2))(2)(H(2)O)(4)]·10H(2)O, the Mn(II) ion is coordinated by two N atoms from two 4-(4H-1,2,4-triazol-4-yl)benzoate ligands and four water mol­ecules in a distorted octa­hedral geometry. The Mn(II) ion and two coordinated water mol­ecules lie on a twofold rotation axis. The water mol­ecules are involved in O—H⋯N and O—H⋯O hydrogen bonds with the triazole N atoms and carboxyl­ate O atoms, yielding a three-dimensional supra­molecular network. π–π inter­actions between the benzene rings [centroid–centroid distance = 3.836 (9) Å] are observed.