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Tetraaquabis[4-(4H-1,2,4-triazol-4-yl)benzoato-κN (1)]manganese(II) decahydrate
In the title compound, [Mn(C(9)H(6)N(3)O(2))(2)(H(2)O)(4)]·10H(2)O, the Mn(II) ion is coordinated by two N atoms from two 4-(4H-1,2,4-triazol-4-yl)benzoate ligands and four water molecules in a distorted octahedral geometry. The Mn(II) ion and two coordinated water molecules lie on a twofold rota...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212150/ https://www.ncbi.nlm.nih.gov/pubmed/22090852 http://dx.doi.org/10.1107/S1600536811025335 |
Sumario: | In the title compound, [Mn(C(9)H(6)N(3)O(2))(2)(H(2)O)(4)]·10H(2)O, the Mn(II) ion is coordinated by two N atoms from two 4-(4H-1,2,4-triazol-4-yl)benzoate ligands and four water molecules in a distorted octahedral geometry. The Mn(II) ion and two coordinated water molecules lie on a twofold rotation axis. The water molecules are involved in O—H⋯N and O—H⋯O hydrogen bonds with the triazole N atoms and carboxylate O atoms, yielding a three-dimensional supramolecular network. π–π interactions between the benzene rings [centroid–centroid distance = 3.836 (9) Å] are observed. |
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