Tetra­aqua­bis­[4-(4H-1,2,4-triazol-4-yl)benzoato-κN (1)]manganese(II) deca­hydrate

In the title compound, [Mn(C(9)H(6)N(3)O(2))(2)(H(2)O)(4)]·10H(2)O, the Mn(II) ion is coordinated by two N atoms from two 4-(4H-1,2,4-triazol-4-yl)benzoate ligands and four water mol­ecules in a distorted octa­hedral geometry. The Mn(II) ion and two coordinated water mol­ecules lie on a twofold rota...

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Detalles Bibliográficos
Autores principales: Piao, Ying-Ai, Xuan, Zhen-Yu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212150/
https://www.ncbi.nlm.nih.gov/pubmed/22090852
http://dx.doi.org/10.1107/S1600536811025335
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author Piao, Ying-Ai
Xuan, Zhen-Yu
author_facet Piao, Ying-Ai
Xuan, Zhen-Yu
author_sort Piao, Ying-Ai
collection PubMed
description In the title compound, [Mn(C(9)H(6)N(3)O(2))(2)(H(2)O)(4)]·10H(2)O, the Mn(II) ion is coordinated by two N atoms from two 4-(4H-1,2,4-triazol-4-yl)benzoate ligands and four water mol­ecules in a distorted octa­hedral geometry. The Mn(II) ion and two coordinated water mol­ecules lie on a twofold rotation axis. The water mol­ecules are involved in O—H⋯N and O—H⋯O hydrogen bonds with the triazole N atoms and carboxyl­ate O atoms, yielding a three-dimensional supra­molecular network. π–π inter­actions between the benzene rings [centroid–centroid distance = 3.836 (9) Å] are observed.
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spelling pubmed-32121502011-11-16 Tetra­aqua­bis­[4-(4H-1,2,4-triazol-4-yl)benzoato-κN (1)]manganese(II) deca­hydrate Piao, Ying-Ai Xuan, Zhen-Yu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(9)H(6)N(3)O(2))(2)(H(2)O)(4)]·10H(2)O, the Mn(II) ion is coordinated by two N atoms from two 4-(4H-1,2,4-triazol-4-yl)benzoate ligands and four water mol­ecules in a distorted octa­hedral geometry. The Mn(II) ion and two coordinated water mol­ecules lie on a twofold rotation axis. The water mol­ecules are involved in O—H⋯N and O—H⋯O hydrogen bonds with the triazole N atoms and carboxyl­ate O atoms, yielding a three-dimensional supra­molecular network. π–π inter­actions between the benzene rings [centroid–centroid distance = 3.836 (9) Å] are observed. International Union of Crystallography 2011-07-09 /pmc/articles/PMC3212150/ /pubmed/22090852 http://dx.doi.org/10.1107/S1600536811025335 Text en © Piao and Xuan 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Piao, Ying-Ai
Xuan, Zhen-Yu
Tetra­aqua­bis­[4-(4H-1,2,4-triazol-4-yl)benzoato-κN (1)]manganese(II) deca­hydrate
title Tetra­aqua­bis­[4-(4H-1,2,4-triazol-4-yl)benzoato-κN (1)]manganese(II) deca­hydrate
title_full Tetra­aqua­bis­[4-(4H-1,2,4-triazol-4-yl)benzoato-κN (1)]manganese(II) deca­hydrate
title_fullStr Tetra­aqua­bis­[4-(4H-1,2,4-triazol-4-yl)benzoato-κN (1)]manganese(II) deca­hydrate
title_full_unstemmed Tetra­aqua­bis­[4-(4H-1,2,4-triazol-4-yl)benzoato-κN (1)]manganese(II) deca­hydrate
title_short Tetra­aqua­bis­[4-(4H-1,2,4-triazol-4-yl)benzoato-κN (1)]manganese(II) deca­hydrate
title_sort tetra­aqua­bis­[4-(4h-1,2,4-triazol-4-yl)benzoato-κn (1)]manganese(ii) deca­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212150/
https://www.ncbi.nlm.nih.gov/pubmed/22090852
http://dx.doi.org/10.1107/S1600536811025335
work_keys_str_mv AT piaoyingai tetraaquabis44h124triazol4ylbenzoatokn1manganeseiidecahydrate
AT xuanzhenyu tetraaquabis44h124triazol4ylbenzoatokn1manganeseiidecahydrate

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