Homopiperazine-1,4-diium bis­[hexa­aqua­cobalt(II)] tris­ulfate

In the title compound, (C(5)H(14)N(2))[Co(H(2)O)(6)](2)(SO(4))(3), the cationic framework is built up of mixed organic–inorganic fragments, namely [Co(H(2)O)(6)](2+) and [C(5)H(14)N(2)](2+). The [Co(H(2)O)(6)](2+) cations form unconnected octa­hedra. Sulfate anions inter­calated between cationic spe...

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Detalles Bibliográficos
Autores principales: Sahbani, Thameur, Smirani Sta, Wajda, S. Al-Deyab, Salem, Rzaigui, Mohamed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212155/
https://www.ncbi.nlm.nih.gov/pubmed/22090857
http://dx.doi.org/10.1107/S1600536811027012
Descripción
Sumario:In the title compound, (C(5)H(14)N(2))[Co(H(2)O)(6)](2)(SO(4))(3), the cationic framework is built up of mixed organic–inorganic fragments, namely [Co(H(2)O)(6)](2+) and [C(5)H(14)N(2)](2+). The [Co(H(2)O)(6)](2+) cations form unconnected octa­hedra. Sulfate anions inter­calated between cationic species connect them via N—H⋯O and O—H⋯O hydrogen bonds and electrostatic inter­actions.

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