Homopiperazine-1,4-diium bis­[hexa­aqua­cobalt(II)] tris­ulfate

In the title compound, (C(5)H(14)N(2))[Co(H(2)O)(6)](2)(SO(4))(3), the cationic framework is built up of mixed organic–inorganic fragments, namely [Co(H(2)O)(6)](2+) and [C(5)H(14)N(2)](2+). The [Co(H(2)O)(6)](2+) cations form unconnected octa­hedra. Sulfate anions inter­calated between cationic spe...

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Detalles Bibliográficos
Autores principales: Sahbani, Thameur, Smirani Sta, Wajda, S. Al-Deyab, Salem, Rzaigui, Mohamed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212155/
https://www.ncbi.nlm.nih.gov/pubmed/22090857
http://dx.doi.org/10.1107/S1600536811027012
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author Sahbani, Thameur
Smirani Sta, Wajda
S. Al-Deyab, Salem
Rzaigui, Mohamed
author_facet Sahbani, Thameur
Smirani Sta, Wajda
S. Al-Deyab, Salem
Rzaigui, Mohamed
author_sort Sahbani, Thameur
collection PubMed
description In the title compound, (C(5)H(14)N(2))[Co(H(2)O)(6)](2)(SO(4))(3), the cationic framework is built up of mixed organic–inorganic fragments, namely [Co(H(2)O)(6)](2+) and [C(5)H(14)N(2)](2+). The [Co(H(2)O)(6)](2+) cations form unconnected octa­hedra. Sulfate anions inter­calated between cationic species connect them via N—H⋯O and O—H⋯O hydrogen bonds and electrostatic inter­actions.
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spelling pubmed-32121552011-11-16 Homopiperazine-1,4-diium bis­[hexa­aqua­cobalt(II)] tris­ulfate Sahbani, Thameur Smirani Sta, Wajda S. Al-Deyab, Salem Rzaigui, Mohamed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(5)H(14)N(2))[Co(H(2)O)(6)](2)(SO(4))(3), the cationic framework is built up of mixed organic–inorganic fragments, namely [Co(H(2)O)(6)](2+) and [C(5)H(14)N(2)](2+). The [Co(H(2)O)(6)](2+) cations form unconnected octa­hedra. Sulfate anions inter­calated between cationic species connect them via N—H⋯O and O—H⋯O hydrogen bonds and electrostatic inter­actions. International Union of Crystallography 2011-07-13 /pmc/articles/PMC3212155/ /pubmed/22090857 http://dx.doi.org/10.1107/S1600536811027012 Text en © Sahbani et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sahbani, Thameur
Smirani Sta, Wajda
S. Al-Deyab, Salem
Rzaigui, Mohamed
Homopiperazine-1,4-diium bis­[hexa­aqua­cobalt(II)] tris­ulfate
title Homopiperazine-1,4-diium bis­[hexa­aqua­cobalt(II)] tris­ulfate
title_full Homopiperazine-1,4-diium bis­[hexa­aqua­cobalt(II)] tris­ulfate
title_fullStr Homopiperazine-1,4-diium bis­[hexa­aqua­cobalt(II)] tris­ulfate
title_full_unstemmed Homopiperazine-1,4-diium bis­[hexa­aqua­cobalt(II)] tris­ulfate
title_short Homopiperazine-1,4-diium bis­[hexa­aqua­cobalt(II)] tris­ulfate
title_sort homopiperazine-1,4-diium bis­[hexa­aqua­cobalt(ii)] tris­ulfate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212155/
https://www.ncbi.nlm.nih.gov/pubmed/22090857
http://dx.doi.org/10.1107/S1600536811027012
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