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Tetrakis[μ-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2) N:N′]tetrakis(μ-methanolato-κ(2) O:O)bis(μ-perchlorato-κ(2) O:O′)tetracopper(II) bis(perchlorate)
The title tetranuclear Cu(II) complex, [Cu(4)(C(12)H(12)N(2)O(2))(4)(CH(3)O)(4)(ClO(4))(2)](ClO(4))(2), is located around an inversion center. Each Cu(II) atom is coordinated by two cis-O atoms from two bridging methanolate anions and two cis-N atoms from two bridging 1,4-bis(4,5-dihydro-1,3-oxaz...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212156/ https://www.ncbi.nlm.nih.gov/pubmed/22090858 http://dx.doi.org/10.1107/S160053681102705X |
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author | Yeh, Chun-Wei Huang, Fu-Chang Jong, Ay Suen, Maw-Cherng |
author_facet | Yeh, Chun-Wei Huang, Fu-Chang Jong, Ay Suen, Maw-Cherng |
author_sort | Yeh, Chun-Wei |
collection | PubMed |
description | The title tetranuclear Cu(II) complex, [Cu(4)(C(12)H(12)N(2)O(2))(4)(CH(3)O)(4)(ClO(4))(2)](ClO(4))(2), is located around an inversion center. Each Cu(II) atom is coordinated by two cis-O atoms from two bridging methanolate anions and two cis-N atoms from two bridging 1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in the basal plane, and is further coordinated by one O atom of the bridging perchlorate anion, forming a distorted square-pyramidal geometry. The Cu⋯Cu separations in the rectangular core are 2.9878 (11) and 6.974 (1) Å. In the asymmetric unit, there are two L ligands with a syn conformation. In one L ligand, the dihedral angles between the central benzene ring and the terminal 4,5-dihydro-1,3-oxazol-2-yl mean planes are 22.1 (4) and 33.1 (4)°, and in the other L ligand the corresponding dihedral angles are 29.3 (4) and 29.9 (4)°. The uncoordinated perchlorate anion is linked with the complex molecules via weak C—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-3212156 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32121562011-11-16 Tetrakis[μ-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2) N:N′]tetrakis(μ-methanolato-κ(2) O:O)bis(μ-perchlorato-κ(2) O:O′)tetracopper(II) bis(perchlorate) Yeh, Chun-Wei Huang, Fu-Chang Jong, Ay Suen, Maw-Cherng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title tetranuclear Cu(II) complex, [Cu(4)(C(12)H(12)N(2)O(2))(4)(CH(3)O)(4)(ClO(4))(2)](ClO(4))(2), is located around an inversion center. Each Cu(II) atom is coordinated by two cis-O atoms from two bridging methanolate anions and two cis-N atoms from two bridging 1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in the basal plane, and is further coordinated by one O atom of the bridging perchlorate anion, forming a distorted square-pyramidal geometry. The Cu⋯Cu separations in the rectangular core are 2.9878 (11) and 6.974 (1) Å. In the asymmetric unit, there are two L ligands with a syn conformation. In one L ligand, the dihedral angles between the central benzene ring and the terminal 4,5-dihydro-1,3-oxazol-2-yl mean planes are 22.1 (4) and 33.1 (4)°, and in the other L ligand the corresponding dihedral angles are 29.3 (4) and 29.9 (4)°. The uncoordinated perchlorate anion is linked with the complex molecules via weak C—H⋯O hydrogen bonds. International Union of Crystallography 2011-07-13 /pmc/articles/PMC3212156/ /pubmed/22090858 http://dx.doi.org/10.1107/S160053681102705X Text en © Yeh et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yeh, Chun-Wei Huang, Fu-Chang Jong, Ay Suen, Maw-Cherng Tetrakis[μ-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2) N:N′]tetrakis(μ-methanolato-κ(2) O:O)bis(μ-perchlorato-κ(2) O:O′)tetracopper(II) bis(perchlorate) |
title | Tetrakis[μ-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2)
N:N′]tetrakis(μ-methanolato-κ(2)
O:O)bis(μ-perchlorato-κ(2)
O:O′)tetracopper(II) bis(perchlorate) |
title_full | Tetrakis[μ-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2)
N:N′]tetrakis(μ-methanolato-κ(2)
O:O)bis(μ-perchlorato-κ(2)
O:O′)tetracopper(II) bis(perchlorate) |
title_fullStr | Tetrakis[μ-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2)
N:N′]tetrakis(μ-methanolato-κ(2)
O:O)bis(μ-perchlorato-κ(2)
O:O′)tetracopper(II) bis(perchlorate) |
title_full_unstemmed | Tetrakis[μ-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2)
N:N′]tetrakis(μ-methanolato-κ(2)
O:O)bis(μ-perchlorato-κ(2)
O:O′)tetracopper(II) bis(perchlorate) |
title_short | Tetrakis[μ-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2)
N:N′]tetrakis(μ-methanolato-κ(2)
O:O)bis(μ-perchlorato-κ(2)
O:O′)tetracopper(II) bis(perchlorate) |
title_sort | tetrakis[μ-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2)
n:n′]tetrakis(μ-methanolato-κ(2)
o:o)bis(μ-perchlorato-κ(2)
o:o′)tetracopper(ii) bis(perchlorate) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212156/ https://www.ncbi.nlm.nih.gov/pubmed/22090858 http://dx.doi.org/10.1107/S160053681102705X |
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