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Tetra­kis[μ-1,4-bis­(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2) N:N′]tetra­kis­(μ-methano­lato-κ(2) O:O)bis­(μ-perchlorato-κ(2) O:O′)tetra­copper(II) bis­(perchlorate)

The title tetra­nuclear Cu(II) complex, [Cu(4)(C(12)H(12)N(2)O(2))(4)(CH(3)O)(4)(ClO(4))(2)](ClO(4))(2), is located around an inversion center. Each Cu(II) atom is coordinated by two cis-O atoms from two bridging methano­late anions and two cis-N atoms from two bridging 1,4-bis­(4,5-dihydro-1,3-oxaz...

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Autores principales: Yeh, Chun-Wei, Huang, Fu-Chang, Jong, Ay, Suen, Maw-Cherng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212156/
https://www.ncbi.nlm.nih.gov/pubmed/22090858
http://dx.doi.org/10.1107/S160053681102705X
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author Yeh, Chun-Wei
Huang, Fu-Chang
Jong, Ay
Suen, Maw-Cherng
author_facet Yeh, Chun-Wei
Huang, Fu-Chang
Jong, Ay
Suen, Maw-Cherng
author_sort Yeh, Chun-Wei
collection PubMed
description The title tetra­nuclear Cu(II) complex, [Cu(4)(C(12)H(12)N(2)O(2))(4)(CH(3)O)(4)(ClO(4))(2)](ClO(4))(2), is located around an inversion center. Each Cu(II) atom is coordinated by two cis-O atoms from two bridging methano­late anions and two cis-N atoms from two bridging 1,4-bis­(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in the basal plane, and is further coordinated by one O atom of the bridging perchlorate anion, forming a distorted square-pyramidal geometry. The Cu⋯Cu separations in the recta­ngular core are 2.9878 (11) and 6.974 (1) Å. In the asymmetric unit, there are two L ligands with a syn conformation. In one L ligand, the dihedral angles between the central benzene ring and the terminal 4,5-dihydro-1,3-oxazol-2-yl mean planes are 22.1 (4) and 33.1 (4)°, and in the other L ligand the corresponding dihedral angles are 29.3 (4) and 29.9 (4)°. The uncoordinated perchlorate anion is linked with the complex mol­ecules via weak C—H⋯O hydrogen bonds.
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spelling pubmed-32121562011-11-16 Tetra­kis[μ-1,4-bis­(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2) N:N′]tetra­kis­(μ-methano­lato-κ(2) O:O)bis­(μ-perchlorato-κ(2) O:O′)tetra­copper(II) bis­(perchlorate) Yeh, Chun-Wei Huang, Fu-Chang Jong, Ay Suen, Maw-Cherng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title tetra­nuclear Cu(II) complex, [Cu(4)(C(12)H(12)N(2)O(2))(4)(CH(3)O)(4)(ClO(4))(2)](ClO(4))(2), is located around an inversion center. Each Cu(II) atom is coordinated by two cis-O atoms from two bridging methano­late anions and two cis-N atoms from two bridging 1,4-bis­(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in the basal plane, and is further coordinated by one O atom of the bridging perchlorate anion, forming a distorted square-pyramidal geometry. The Cu⋯Cu separations in the recta­ngular core are 2.9878 (11) and 6.974 (1) Å. In the asymmetric unit, there are two L ligands with a syn conformation. In one L ligand, the dihedral angles between the central benzene ring and the terminal 4,5-dihydro-1,3-oxazol-2-yl mean planes are 22.1 (4) and 33.1 (4)°, and in the other L ligand the corresponding dihedral angles are 29.3 (4) and 29.9 (4)°. The uncoordinated perchlorate anion is linked with the complex mol­ecules via weak C—H⋯O hydrogen bonds. International Union of Crystallography 2011-07-13 /pmc/articles/PMC3212156/ /pubmed/22090858 http://dx.doi.org/10.1107/S160053681102705X Text en © Yeh et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yeh, Chun-Wei
Huang, Fu-Chang
Jong, Ay
Suen, Maw-Cherng
Tetra­kis[μ-1,4-bis­(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2) N:N′]tetra­kis­(μ-methano­lato-κ(2) O:O)bis­(μ-perchlorato-κ(2) O:O′)tetra­copper(II) bis­(perchlorate)
title Tetra­kis[μ-1,4-bis­(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2) N:N′]tetra­kis­(μ-methano­lato-κ(2) O:O)bis­(μ-perchlorato-κ(2) O:O′)tetra­copper(II) bis­(perchlorate)
title_full Tetra­kis[μ-1,4-bis­(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2) N:N′]tetra­kis­(μ-methano­lato-κ(2) O:O)bis­(μ-perchlorato-κ(2) O:O′)tetra­copper(II) bis­(perchlorate)
title_fullStr Tetra­kis[μ-1,4-bis­(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2) N:N′]tetra­kis­(μ-methano­lato-κ(2) O:O)bis­(μ-perchlorato-κ(2) O:O′)tetra­copper(II) bis­(perchlorate)
title_full_unstemmed Tetra­kis[μ-1,4-bis­(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2) N:N′]tetra­kis­(μ-methano­lato-κ(2) O:O)bis­(μ-perchlorato-κ(2) O:O′)tetra­copper(II) bis­(perchlorate)
title_short Tetra­kis[μ-1,4-bis­(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2) N:N′]tetra­kis­(μ-methano­lato-κ(2) O:O)bis­(μ-perchlorato-κ(2) O:O′)tetra­copper(II) bis­(perchlorate)
title_sort tetra­kis[μ-1,4-bis­(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2) n:n′]tetra­kis­(μ-methano­lato-κ(2) o:o)bis­(μ-perchlorato-κ(2) o:o′)tetra­copper(ii) bis­(perchlorate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212156/
https://www.ncbi.nlm.nih.gov/pubmed/22090858
http://dx.doi.org/10.1107/S160053681102705X
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