catena-Poly[(μ-2-amino-1,3,4-thia­diazole-κ(2) N (3):N (4))di-μ-chlorido-cadmium]

In the title coordination polymer, [CdCl(2)(C(2)H(3)N(3)S)](n), the Cd(II) cation is coordinated by four Cl(−) anions and two N atoms from two trans 2-amino-1,3,4-thia­diazole (L) ligands in a distorted octa­hedral geometry. The L ligand and Cl(−) anions bridge adjacent Cd cations, forming a polymer...

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Detalles Bibliográficos
Autores principales: Suen, Maw-Cherng, Yeh, Chun-Wei, Jou, Chi-Hsiung
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212157/
https://www.ncbi.nlm.nih.gov/pubmed/22090859
http://dx.doi.org/10.1107/S1600536811027048
Descripción
Sumario:In the title coordination polymer, [CdCl(2)(C(2)H(3)N(3)S)](n), the Cd(II) cation is coordinated by four Cl(−) anions and two N atoms from two trans 2-amino-1,3,4-thia­diazole (L) ligands in a distorted octa­hedral geometry. The L ligand and Cl(−) anions bridge adjacent Cd cations, forming a polymeric chain along the b axis; the separation between adjacent Cd cations is 3.619 (1) Å. In the crystal, the polymeric chains are inter­linking through N—H⋯Cl hydrogen bonds between the L ligands and Cl(−) anions.

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