catena-Poly[(μ-2-amino-1,3,4-thia­diazole-κ(2) N (3):N (4))di-μ-chlorido-cadmium]

In the title coordination polymer, [CdCl(2)(C(2)H(3)N(3)S)](n), the Cd(II) cation is coordinated by four Cl(−) anions and two N atoms from two trans 2-amino-1,3,4-thia­diazole (L) ligands in a distorted octa­hedral geometry. The L ligand and Cl(−) anions bridge adjacent Cd cations, forming a polymer...

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Detalles Bibliográficos
Autores principales: Suen, Maw-Cherng, Yeh, Chun-Wei, Jou, Chi-Hsiung
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212157/
https://www.ncbi.nlm.nih.gov/pubmed/22090859
http://dx.doi.org/10.1107/S1600536811027048
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author Suen, Maw-Cherng
Yeh, Chun-Wei
Jou, Chi-Hsiung
author_facet Suen, Maw-Cherng
Yeh, Chun-Wei
Jou, Chi-Hsiung
author_sort Suen, Maw-Cherng
collection PubMed
description In the title coordination polymer, [CdCl(2)(C(2)H(3)N(3)S)](n), the Cd(II) cation is coordinated by four Cl(−) anions and two N atoms from two trans 2-amino-1,3,4-thia­diazole (L) ligands in a distorted octa­hedral geometry. The L ligand and Cl(−) anions bridge adjacent Cd cations, forming a polymeric chain along the b axis; the separation between adjacent Cd cations is 3.619 (1) Å. In the crystal, the polymeric chains are inter­linking through N—H⋯Cl hydrogen bonds between the L ligands and Cl(−) anions.
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spelling pubmed-32121572011-11-16 catena-Poly[(μ-2-amino-1,3,4-thia­diazole-κ(2) N (3):N (4))di-μ-chlorido-cadmium] Suen, Maw-Cherng Yeh, Chun-Wei Jou, Chi-Hsiung Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [CdCl(2)(C(2)H(3)N(3)S)](n), the Cd(II) cation is coordinated by four Cl(−) anions and two N atoms from two trans 2-amino-1,3,4-thia­diazole (L) ligands in a distorted octa­hedral geometry. The L ligand and Cl(−) anions bridge adjacent Cd cations, forming a polymeric chain along the b axis; the separation between adjacent Cd cations is 3.619 (1) Å. In the crystal, the polymeric chains are inter­linking through N—H⋯Cl hydrogen bonds between the L ligands and Cl(−) anions. International Union of Crystallography 2011-07-13 /pmc/articles/PMC3212157/ /pubmed/22090859 http://dx.doi.org/10.1107/S1600536811027048 Text en © Suen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Suen, Maw-Cherng
Yeh, Chun-Wei
Jou, Chi-Hsiung
catena-Poly[(μ-2-amino-1,3,4-thia­diazole-κ(2) N (3):N (4))di-μ-chlorido-cadmium]
title catena-Poly[(μ-2-amino-1,3,4-thia­diazole-κ(2) N (3):N (4))di-μ-chlorido-cadmium]
title_full catena-Poly[(μ-2-amino-1,3,4-thia­diazole-κ(2) N (3):N (4))di-μ-chlorido-cadmium]
title_fullStr catena-Poly[(μ-2-amino-1,3,4-thia­diazole-κ(2) N (3):N (4))di-μ-chlorido-cadmium]
title_full_unstemmed catena-Poly[(μ-2-amino-1,3,4-thia­diazole-κ(2) N (3):N (4))di-μ-chlorido-cadmium]
title_short catena-Poly[(μ-2-amino-1,3,4-thia­diazole-κ(2) N (3):N (4))di-μ-chlorido-cadmium]
title_sort catena-poly[(μ-2-amino-1,3,4-thia­diazole-κ(2) n (3):n (4))di-μ-chlorido-cadmium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212157/
https://www.ncbi.nlm.nih.gov/pubmed/22090859
http://dx.doi.org/10.1107/S1600536811027048
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