(E)-N-(Ferrocenyl­methyl­idene)(pyridin-3-yl)methanamine

In the title compound, [Fe(C(5)H(5))(C(12)H(11)N(2))], the cyclo­penta­dienyl rings are present in an eclipsed conformation. The imine is E-configured. In the crystal, C—H⋯N inter­actions involving both N atoms connect the mol­ecules into two undulating sheets perpendicular to the b axis. The centro...

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Detalles Bibliográficos
Autores principales: Adams, Nadia, Gerber, Thomas, McCleland, Cedric, Betz, Richard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212159/
https://www.ncbi.nlm.nih.gov/pubmed/22090861
http://dx.doi.org/10.1107/S1600536811027346
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author Adams, Nadia
Gerber, Thomas
McCleland, Cedric
Betz, Richard
author_facet Adams, Nadia
Gerber, Thomas
McCleland, Cedric
Betz, Richard
author_sort Adams, Nadia
collection PubMed
description In the title compound, [Fe(C(5)H(5))(C(12)H(11)N(2))], the cyclo­penta­dienyl rings are present in an eclipsed conformation. The imine is E-configured. In the crystal, C—H⋯N inter­actions involving both N atoms connect the mol­ecules into two undulating sheets perpendicular to the b axis. The centroid–centroid distance between the two aromatic systems in the ferrocenyl moiety is 3.2928 (18) Å. A C–H⋯π inter­action is also present.
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spelling pubmed-32121592011-11-16 (E)-N-(Ferrocenyl­methyl­idene)(pyridin-3-yl)methanamine Adams, Nadia Gerber, Thomas McCleland, Cedric Betz, Richard Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(5)H(5))(C(12)H(11)N(2))], the cyclo­penta­dienyl rings are present in an eclipsed conformation. The imine is E-configured. In the crystal, C—H⋯N inter­actions involving both N atoms connect the mol­ecules into two undulating sheets perpendicular to the b axis. The centroid–centroid distance between the two aromatic systems in the ferrocenyl moiety is 3.2928 (18) Å. A C–H⋯π inter­action is also present. International Union of Crystallography 2011-07-13 /pmc/articles/PMC3212159/ /pubmed/22090861 http://dx.doi.org/10.1107/S1600536811027346 Text en © Adams et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Adams, Nadia
Gerber, Thomas
McCleland, Cedric
Betz, Richard
(E)-N-(Ferrocenyl­methyl­idene)(pyridin-3-yl)methanamine
title (E)-N-(Ferrocenyl­methyl­idene)(pyridin-3-yl)methanamine
title_full (E)-N-(Ferrocenyl­methyl­idene)(pyridin-3-yl)methanamine
title_fullStr (E)-N-(Ferrocenyl­methyl­idene)(pyridin-3-yl)methanamine
title_full_unstemmed (E)-N-(Ferrocenyl­methyl­idene)(pyridin-3-yl)methanamine
title_short (E)-N-(Ferrocenyl­methyl­idene)(pyridin-3-yl)methanamine
title_sort (e)-n-(ferrocenyl­methyl­idene)(pyridin-3-yl)methanamine
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212159/
https://www.ncbi.nlm.nih.gov/pubmed/22090861
http://dx.doi.org/10.1107/S1600536811027346
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AT mcclelandcedric enferrocenylmethylidenepyridin3ylmethanamine
AT betzrichard enferrocenylmethylidenepyridin3ylmethanamine

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