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Poly[μ(4)-glutarato-di-μ(3)-glutarato-bis­(1,10-phenanthroline)diyttrium(III)]

In the title complex, [Y(2)(C(5)H(6)O(4))(3)(C(12)H(8)N(2))(2)](n), three glutarate groups and two 1,10-phenanthroline mol­ecules surround the two Y(III) ions. Both Y(III) ions are coordinated by two N atoms from the 1,10-phenanthroline, seven O atoms from five glutarate groups in a distorted tricap...

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Detalles Bibliográficos
Autores principales: Jin, Ling, Zhu, Hong-lin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212162/
https://www.ncbi.nlm.nih.gov/pubmed/22090864
http://dx.doi.org/10.1107/S1600536811027188
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author Jin, Ling
Zhu, Hong-lin
author_facet Jin, Ling
Zhu, Hong-lin
author_sort Jin, Ling
collection PubMed
description In the title complex, [Y(2)(C(5)H(6)O(4))(3)(C(12)H(8)N(2))(2)](n), three glutarate groups and two 1,10-phenanthroline mol­ecules surround the two Y(III) ions. Both Y(III) ions are coordinated by two N atoms from the 1,10-phenanthroline, seven O atoms from five glutarate groups in a distorted tricapped trigonal–prismatic geometry. The Y(III) ions are bridged by glutarate ligands in three modes, forming a layered, polymeric structure. The resulting layers are assembled by π–π stacking inter­actions [centroid–centroid distances = 3.740 (3) and 3.571 (3) Å] into a three-dimensional supra­molecular architecture.
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spelling pubmed-32121622011-11-16 Poly[μ(4)-glutarato-di-μ(3)-glutarato-bis­(1,10-phenanthroline)diyttrium(III)] Jin, Ling Zhu, Hong-lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Y(2)(C(5)H(6)O(4))(3)(C(12)H(8)N(2))(2)](n), three glutarate groups and two 1,10-phenanthroline mol­ecules surround the two Y(III) ions. Both Y(III) ions are coordinated by two N atoms from the 1,10-phenanthroline, seven O atoms from five glutarate groups in a distorted tricapped trigonal–prismatic geometry. The Y(III) ions are bridged by glutarate ligands in three modes, forming a layered, polymeric structure. The resulting layers are assembled by π–π stacking inter­actions [centroid–centroid distances = 3.740 (3) and 3.571 (3) Å] into a three-dimensional supra­molecular architecture. International Union of Crystallography 2011-07-13 /pmc/articles/PMC3212162/ /pubmed/22090864 http://dx.doi.org/10.1107/S1600536811027188 Text en © Jin and Zhu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jin, Ling
Zhu, Hong-lin
Poly[μ(4)-glutarato-di-μ(3)-glutarato-bis­(1,10-phenanthroline)diyttrium(III)]
title Poly[μ(4)-glutarato-di-μ(3)-glutarato-bis­(1,10-phenanthroline)diyttrium(III)]
title_full Poly[μ(4)-glutarato-di-μ(3)-glutarato-bis­(1,10-phenanthroline)diyttrium(III)]
title_fullStr Poly[μ(4)-glutarato-di-μ(3)-glutarato-bis­(1,10-phenanthroline)diyttrium(III)]
title_full_unstemmed Poly[μ(4)-glutarato-di-μ(3)-glutarato-bis­(1,10-phenanthroline)diyttrium(III)]
title_short Poly[μ(4)-glutarato-di-μ(3)-glutarato-bis­(1,10-phenanthroline)diyttrium(III)]
title_sort poly[μ(4)-glutarato-di-μ(3)-glutarato-bis­(1,10-phenanthroline)diyttrium(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212162/
https://www.ncbi.nlm.nih.gov/pubmed/22090864
http://dx.doi.org/10.1107/S1600536811027188
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