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Poly[μ(4)-glutarato-di-μ(3)-glutarato-bis(1,10-phenanthroline)diyttrium(III)]
In the title complex, [Y(2)(C(5)H(6)O(4))(3)(C(12)H(8)N(2))(2)](n), three glutarate groups and two 1,10-phenanthroline molecules surround the two Y(III) ions. Both Y(III) ions are coordinated by two N atoms from the 1,10-phenanthroline, seven O atoms from five glutarate groups in a distorted tricap...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212162/ https://www.ncbi.nlm.nih.gov/pubmed/22090864 http://dx.doi.org/10.1107/S1600536811027188 |
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author | Jin, Ling Zhu, Hong-lin |
author_facet | Jin, Ling Zhu, Hong-lin |
author_sort | Jin, Ling |
collection | PubMed |
description | In the title complex, [Y(2)(C(5)H(6)O(4))(3)(C(12)H(8)N(2))(2)](n), three glutarate groups and two 1,10-phenanthroline molecules surround the two Y(III) ions. Both Y(III) ions are coordinated by two N atoms from the 1,10-phenanthroline, seven O atoms from five glutarate groups in a distorted tricapped trigonal–prismatic geometry. The Y(III) ions are bridged by glutarate ligands in three modes, forming a layered, polymeric structure. The resulting layers are assembled by π–π stacking interactions [centroid–centroid distances = 3.740 (3) and 3.571 (3) Å] into a three-dimensional supramolecular architecture. |
format | Online Article Text |
id | pubmed-3212162 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32121622011-11-16 Poly[μ(4)-glutarato-di-μ(3)-glutarato-bis(1,10-phenanthroline)diyttrium(III)] Jin, Ling Zhu, Hong-lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Y(2)(C(5)H(6)O(4))(3)(C(12)H(8)N(2))(2)](n), three glutarate groups and two 1,10-phenanthroline molecules surround the two Y(III) ions. Both Y(III) ions are coordinated by two N atoms from the 1,10-phenanthroline, seven O atoms from five glutarate groups in a distorted tricapped trigonal–prismatic geometry. The Y(III) ions are bridged by glutarate ligands in three modes, forming a layered, polymeric structure. The resulting layers are assembled by π–π stacking interactions [centroid–centroid distances = 3.740 (3) and 3.571 (3) Å] into a three-dimensional supramolecular architecture. International Union of Crystallography 2011-07-13 /pmc/articles/PMC3212162/ /pubmed/22090864 http://dx.doi.org/10.1107/S1600536811027188 Text en © Jin and Zhu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Jin, Ling Zhu, Hong-lin Poly[μ(4)-glutarato-di-μ(3)-glutarato-bis(1,10-phenanthroline)diyttrium(III)] |
title | Poly[μ(4)-glutarato-di-μ(3)-glutarato-bis(1,10-phenanthroline)diyttrium(III)] |
title_full | Poly[μ(4)-glutarato-di-μ(3)-glutarato-bis(1,10-phenanthroline)diyttrium(III)] |
title_fullStr | Poly[μ(4)-glutarato-di-μ(3)-glutarato-bis(1,10-phenanthroline)diyttrium(III)] |
title_full_unstemmed | Poly[μ(4)-glutarato-di-μ(3)-glutarato-bis(1,10-phenanthroline)diyttrium(III)] |
title_short | Poly[μ(4)-glutarato-di-μ(3)-glutarato-bis(1,10-phenanthroline)diyttrium(III)] |
title_sort | poly[μ(4)-glutarato-di-μ(3)-glutarato-bis(1,10-phenanthroline)diyttrium(iii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212162/ https://www.ncbi.nlm.nih.gov/pubmed/22090864 http://dx.doi.org/10.1107/S1600536811027188 |
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