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Tetra-μ-acetato-bis[(1,3-benzothiazole)copper(II)](Cu—Cu)
The title compound, [Cu(2)(CH(3)CO(2))(4)(C(7)H(5)NS)(2)] or [(C(7)H(5)NS)Cu](2)(μ-O(2)CCH(3))(4), crystallizes with one molecule per unit cell. The coordination number of copper is six with four basal O atoms, one axial N atom and one axial Cu atom. Four acetate ligands act as bidentate linker and...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212163/ https://www.ncbi.nlm.nih.gov/pubmed/22090865 http://dx.doi.org/10.1107/S1600536811027140 |
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author | Hermle, Johannes Meyer, Gerd |
author_facet | Hermle, Johannes Meyer, Gerd |
author_sort | Hermle, Johannes |
collection | PubMed |
description | The title compound, [Cu(2)(CH(3)CO(2))(4)(C(7)H(5)NS)(2)] or [(C(7)H(5)NS)Cu](2)(μ-O(2)CCH(3))(4), crystallizes with one molecule per unit cell. The coordination number of copper is six with four basal O atoms, one axial N atom and one axial Cu atom. Four acetate ligands act as bidentate linker and connect two Cu atoms, with a crystallographic inversion center located at the mid-point of the Cu—Cu bond. The acetate ligands form slightly distorted square planes around each metal ion, while the copper ions are displaced by 0.2089 (4) Å from these planes towards the N atoms. Thus, the Cu—Cu distance is elongated to 2.6378 (7) Å, compared with the 2.2180 (7) Å distance between the two basal planes. The angle between the basal plane and the Cu—N bond is 4.84 (6)°. |
format | Online Article Text |
id | pubmed-3212163 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32121632011-11-16 Tetra-μ-acetato-bis[(1,3-benzothiazole)copper(II)](Cu—Cu) Hermle, Johannes Meyer, Gerd Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(2)(CH(3)CO(2))(4)(C(7)H(5)NS)(2)] or [(C(7)H(5)NS)Cu](2)(μ-O(2)CCH(3))(4), crystallizes with one molecule per unit cell. The coordination number of copper is six with four basal O atoms, one axial N atom and one axial Cu atom. Four acetate ligands act as bidentate linker and connect two Cu atoms, with a crystallographic inversion center located at the mid-point of the Cu—Cu bond. The acetate ligands form slightly distorted square planes around each metal ion, while the copper ions are displaced by 0.2089 (4) Å from these planes towards the N atoms. Thus, the Cu—Cu distance is elongated to 2.6378 (7) Å, compared with the 2.2180 (7) Å distance between the two basal planes. The angle between the basal plane and the Cu—N bond is 4.84 (6)°. International Union of Crystallography 2011-07-13 /pmc/articles/PMC3212163/ /pubmed/22090865 http://dx.doi.org/10.1107/S1600536811027140 Text en © Hermle and Meyer 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hermle, Johannes Meyer, Gerd Tetra-μ-acetato-bis[(1,3-benzothiazole)copper(II)](Cu—Cu) |
title | Tetra-μ-acetato-bis[(1,3-benzothiazole)copper(II)](Cu—Cu) |
title_full | Tetra-μ-acetato-bis[(1,3-benzothiazole)copper(II)](Cu—Cu) |
title_fullStr | Tetra-μ-acetato-bis[(1,3-benzothiazole)copper(II)](Cu—Cu) |
title_full_unstemmed | Tetra-μ-acetato-bis[(1,3-benzothiazole)copper(II)](Cu—Cu) |
title_short | Tetra-μ-acetato-bis[(1,3-benzothiazole)copper(II)](Cu—Cu) |
title_sort | tetra-μ-acetato-bis[(1,3-benzothiazole)copper(ii)](cu—cu) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212163/ https://www.ncbi.nlm.nih.gov/pubmed/22090865 http://dx.doi.org/10.1107/S1600536811027140 |
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