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Tetra-μ-acetato-bis­[(1,3-benzothia­zole)copper(II)](Cu—Cu)

The title compound, [Cu(2)(CH(3)CO(2))(4)(C(7)H(5)NS)(2)] or [(C(7)H(5)NS)Cu](2)(μ-O(2)CCH(3))(4), crystallizes with one mol­ecule per unit cell. The coordination number of copper is six with four basal O atoms, one axial N atom and one axial Cu atom. Four acetate ligands act as bidentate linker and...

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Autores principales: Hermle, Johannes, Meyer, Gerd
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212163/
https://www.ncbi.nlm.nih.gov/pubmed/22090865
http://dx.doi.org/10.1107/S1600536811027140
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author Hermle, Johannes
Meyer, Gerd
author_facet Hermle, Johannes
Meyer, Gerd
author_sort Hermle, Johannes
collection PubMed
description The title compound, [Cu(2)(CH(3)CO(2))(4)(C(7)H(5)NS)(2)] or [(C(7)H(5)NS)Cu](2)(μ-O(2)CCH(3))(4), crystallizes with one mol­ecule per unit cell. The coordination number of copper is six with four basal O atoms, one axial N atom and one axial Cu atom. Four acetate ligands act as bidentate linker and connect two Cu atoms, with a crystallographic inversion center located at the mid-point of the Cu—Cu bond. The acetate ligands form slightly distorted square planes around each metal ion, while the copper ions are displaced by 0.2089 (4) Å from these planes towards the N atoms. Thus, the Cu—Cu distance is elongated to 2.6378 (7) Å, compared with the 2.2180 (7) Å distance between the two basal planes. The angle between the basal plane and the Cu—N bond is 4.84 (6)°.
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spelling pubmed-32121632011-11-16 Tetra-μ-acetato-bis­[(1,3-benzothia­zole)copper(II)](Cu—Cu) Hermle, Johannes Meyer, Gerd Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(2)(CH(3)CO(2))(4)(C(7)H(5)NS)(2)] or [(C(7)H(5)NS)Cu](2)(μ-O(2)CCH(3))(4), crystallizes with one mol­ecule per unit cell. The coordination number of copper is six with four basal O atoms, one axial N atom and one axial Cu atom. Four acetate ligands act as bidentate linker and connect two Cu atoms, with a crystallographic inversion center located at the mid-point of the Cu—Cu bond. The acetate ligands form slightly distorted square planes around each metal ion, while the copper ions are displaced by 0.2089 (4) Å from these planes towards the N atoms. Thus, the Cu—Cu distance is elongated to 2.6378 (7) Å, compared with the 2.2180 (7) Å distance between the two basal planes. The angle between the basal plane and the Cu—N bond is 4.84 (6)°. International Union of Crystallography 2011-07-13 /pmc/articles/PMC3212163/ /pubmed/22090865 http://dx.doi.org/10.1107/S1600536811027140 Text en © Hermle and Meyer 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hermle, Johannes
Meyer, Gerd
Tetra-μ-acetato-bis­[(1,3-benzothia­zole)copper(II)](Cu—Cu)
title Tetra-μ-acetato-bis­[(1,3-benzothia­zole)copper(II)](Cu—Cu)
title_full Tetra-μ-acetato-bis­[(1,3-benzothia­zole)copper(II)](Cu—Cu)
title_fullStr Tetra-μ-acetato-bis­[(1,3-benzothia­zole)copper(II)](Cu—Cu)
title_full_unstemmed Tetra-μ-acetato-bis­[(1,3-benzothia­zole)copper(II)](Cu—Cu)
title_short Tetra-μ-acetato-bis­[(1,3-benzothia­zole)copper(II)](Cu—Cu)
title_sort tetra-μ-acetato-bis­[(1,3-benzothia­zole)copper(ii)](cu—cu)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212163/
https://www.ncbi.nlm.nih.gov/pubmed/22090865
http://dx.doi.org/10.1107/S1600536811027140
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