Hexachloridobis­{μ(2)-2-(piperazin-1-yl)-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine}­trizinc dihydrate

In the trinuclear title compound, [Zn(3)Cl(6)(C(13)H(20)N(4))(2)]·2H(2)O, each terminal Zn(II) atom is coordinated by an N(3) donor set from the Schiff base ligands and two Cl atoms in a distorted square-pyramidal geometry. The central Zn(II) atom is tetra­hedrally coordinated by two piperazine N at...

Descripción completa

Detalles Bibliográficos
Autores principales: Suleiman Gwaram, Nura, Khaledi, Hamid, Mohd Ali, Hapipah
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212165/
https://www.ncbi.nlm.nih.gov/pubmed/22090867
http://dx.doi.org/10.1107/S1600536811027437
_version_ 1782215933236871168
author Suleiman Gwaram, Nura
Khaledi, Hamid
Mohd Ali, Hapipah
author_facet Suleiman Gwaram, Nura
Khaledi, Hamid
Mohd Ali, Hapipah
author_sort Suleiman Gwaram, Nura
collection PubMed
description In the trinuclear title compound, [Zn(3)Cl(6)(C(13)H(20)N(4))(2)]·2H(2)O, each terminal Zn(II) atom is coordinated by an N(3) donor set from the Schiff base ligands and two Cl atoms in a distorted square-pyramidal geometry. The central Zn(II) atom is tetra­hedrally coordinated by two piperazine N atoms from two Schiff base ligands and two Cl atoms. The piperazine rings adopt chair conformations. In the crystal structure, adjacent complex mol­ecules are linked into a three-dimensional network via N—H⋯O, C—H⋯Cl and C—H⋯O hydrogen bonds. The structure includes two water mol­ecules, one of which is disordered over two positions with occupancies of 0.753 (15) and 0.247 (15).
format Online
Article
Text
id pubmed-3212165
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32121652011-11-16 Hexachloridobis­{μ(2)-2-(piperazin-1-yl)-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine}­trizinc dihydrate Suleiman Gwaram, Nura Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the trinuclear title compound, [Zn(3)Cl(6)(C(13)H(20)N(4))(2)]·2H(2)O, each terminal Zn(II) atom is coordinated by an N(3) donor set from the Schiff base ligands and two Cl atoms in a distorted square-pyramidal geometry. The central Zn(II) atom is tetra­hedrally coordinated by two piperazine N atoms from two Schiff base ligands and two Cl atoms. The piperazine rings adopt chair conformations. In the crystal structure, adjacent complex mol­ecules are linked into a three-dimensional network via N—H⋯O, C—H⋯Cl and C—H⋯O hydrogen bonds. The structure includes two water mol­ecules, one of which is disordered over two positions with occupancies of 0.753 (15) and 0.247 (15). International Union of Crystallography 2011-07-13 /pmc/articles/PMC3212165/ /pubmed/22090867 http://dx.doi.org/10.1107/S1600536811027437 Text en © Suleiman Gwaram et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Suleiman Gwaram, Nura
Khaledi, Hamid
Mohd Ali, Hapipah
Hexachloridobis­{μ(2)-2-(piperazin-1-yl)-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine}­trizinc dihydrate
title Hexachloridobis­{μ(2)-2-(piperazin-1-yl)-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine}­trizinc dihydrate
title_full Hexachloridobis­{μ(2)-2-(piperazin-1-yl)-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine}­trizinc dihydrate
title_fullStr Hexachloridobis­{μ(2)-2-(piperazin-1-yl)-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine}­trizinc dihydrate
title_full_unstemmed Hexachloridobis­{μ(2)-2-(piperazin-1-yl)-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine}­trizinc dihydrate
title_short Hexachloridobis­{μ(2)-2-(piperazin-1-yl)-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine}­trizinc dihydrate
title_sort hexachloridobis­{μ(2)-2-(piperazin-1-yl)-n-[1-(2-pyrid­yl)ethyl­idene]ethanamine}­trizinc dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212165/
https://www.ncbi.nlm.nih.gov/pubmed/22090867
http://dx.doi.org/10.1107/S1600536811027437
work_keys_str_mv AT suleimangwaramnura hexachloridobism22piperazin1yln12pyridylethylideneethanaminetrizincdihydrate
AT khaledihamid hexachloridobism22piperazin1yln12pyridylethylideneethanaminetrizincdihydrate
AT mohdalihapipah hexachloridobism22piperazin1yln12pyridylethylideneethanaminetrizincdihydrate

Ejemplares similares