Bis(acetonitrile-κN)dichlorido(η(4)-cyclo­octa-1,5-diene)ruthenium(II) acetonitrile monosolvate

In the title Ru(II) complex, [RuCl(2)(C(8)H(12))(C(2)H(3)N)(2)]·CH(3)CN, the metal ion is coordinated to the centers of each of the double bonds of the cyclo­octa­diene ligand, to two chloride ions (in cis positions) and to two N-atom donors (from MeCN mol­ecules) that complete the coordination sphe...

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Autores principales: Chiririwa, Haleden, Meijboom, Reinout, Owalude, Samson O., Eke, Uche B., Arderne, Charmaine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212168/
https://www.ncbi.nlm.nih.gov/pubmed/22090870
http://dx.doi.org/10.1107/S1600536811027723
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author Chiririwa, Haleden
Meijboom, Reinout
Owalude, Samson O.
Eke, Uche B.
Arderne, Charmaine
author_facet Chiririwa, Haleden
Meijboom, Reinout
Owalude, Samson O.
Eke, Uche B.
Arderne, Charmaine
author_sort Chiririwa, Haleden
collection PubMed
description In the title Ru(II) complex, [RuCl(2)(C(8)H(12))(C(2)H(3)N)(2)]·CH(3)CN, the metal ion is coordinated to the centers of each of the double bonds of the cyclo­octa­diene ligand, to two chloride ions (in cis positions) and to two N-atom donors (from MeCN mol­ecules) that complete the coordination sphere for the neutral complex. The coordination about the Ru(II) atom can thus be considered to be octa­hedral with a slightly trigonal distortion. There is also one acetonitrile solvent mol­ecule per mol­ecule which is outside the coordination sphere of the ruthenium atom.
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spelling pubmed-32121682011-11-16 Bis(acetonitrile-κN)dichlorido(η(4)-cyclo­octa-1,5-diene)ruthenium(II) acetonitrile monosolvate Chiririwa, Haleden Meijboom, Reinout Owalude, Samson O. Eke, Uche B. Arderne, Charmaine Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title Ru(II) complex, [RuCl(2)(C(8)H(12))(C(2)H(3)N)(2)]·CH(3)CN, the metal ion is coordinated to the centers of each of the double bonds of the cyclo­octa­diene ligand, to two chloride ions (in cis positions) and to two N-atom donors (from MeCN mol­ecules) that complete the coordination sphere for the neutral complex. The coordination about the Ru(II) atom can thus be considered to be octa­hedral with a slightly trigonal distortion. There is also one acetonitrile solvent mol­ecule per mol­ecule which is outside the coordination sphere of the ruthenium atom. International Union of Crystallography 2011-07-16 /pmc/articles/PMC3212168/ /pubmed/22090870 http://dx.doi.org/10.1107/S1600536811027723 Text en © Chiririwa et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chiririwa, Haleden
Meijboom, Reinout
Owalude, Samson O.
Eke, Uche B.
Arderne, Charmaine
Bis(acetonitrile-κN)dichlorido(η(4)-cyclo­octa-1,5-diene)ruthenium(II) acetonitrile monosolvate
title Bis(acetonitrile-κN)dichlorido(η(4)-cyclo­octa-1,5-diene)ruthenium(II) acetonitrile monosolvate
title_full Bis(acetonitrile-κN)dichlorido(η(4)-cyclo­octa-1,5-diene)ruthenium(II) acetonitrile monosolvate
title_fullStr Bis(acetonitrile-κN)dichlorido(η(4)-cyclo­octa-1,5-diene)ruthenium(II) acetonitrile monosolvate
title_full_unstemmed Bis(acetonitrile-κN)dichlorido(η(4)-cyclo­octa-1,5-diene)ruthenium(II) acetonitrile monosolvate
title_short Bis(acetonitrile-κN)dichlorido(η(4)-cyclo­octa-1,5-diene)ruthenium(II) acetonitrile monosolvate
title_sort bis(acetonitrile-κn)dichlorido(η(4)-cyclo­octa-1,5-diene)ruthenium(ii) acetonitrile monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212168/
https://www.ncbi.nlm.nih.gov/pubmed/22090870
http://dx.doi.org/10.1107/S1600536811027723
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