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Tetra-μ(2)-acetato-diaqua­bis­(μ(2)-2-{[1,3-dihy­droxy-2-(oxidometh­yl)propan-2-yl]imino­meth­yl}phenolato)trimanganese(II,III) acetonitrile disolvate dihydrate

In the title complex, [Mn(II)Mn(III) (2)(C(11)H(13)NO(4))(2)(CH(3)CO(2))(4)(H(2)O)(2)]·2CH(3)CN·2H(2)O, there are two Mn(III) and one Mn(II) atoms. The Mn(II) atom lies on an inversion center and the Mn(III)—Mn(II)—Mn(III) angle is therefore 180°, as required by crystallographic symmetry. The Mn(III...

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Detalles Bibliográficos
Autores principales: Guo, Yuhua, Huang, Jianping, Huang, Yong, Wang, Junyue, Yu, Youzhu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212170/
https://www.ncbi.nlm.nih.gov/pubmed/22090872
http://dx.doi.org/10.1107/S1600536811027899
Descripción
Sumario:In the title complex, [Mn(II)Mn(III) (2)(C(11)H(13)NO(4))(2)(CH(3)CO(2))(4)(H(2)O)(2)]·2CH(3)CN·2H(2)O, there are two Mn(III) and one Mn(II) atoms. The Mn(II) atom lies on an inversion center and the Mn(III)—Mn(II)—Mn(III) angle is therefore 180°, as required by crystallographic symmetry. The Mn(III) and Mn(II) atoms are six-coordinated in a distorted octa­hedral geometry. In the crystal, complex mol­ecules and solvent mol­ecules are linked into a three-dimensional network by O—H⋯O and O—H⋯N hydrogen-bonding inter­actions.