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Tetra-μ(2)-acetato-diaquabis(μ(2)-2-{[1,3-dihydroxy-2-(oxidomethyl)propan-2-yl]iminomethyl}phenolato)trimanganese(II,III) acetonitrile disolvate dihydrate
In the title complex, [Mn(II)Mn(III) (2)(C(11)H(13)NO(4))(2)(CH(3)CO(2))(4)(H(2)O)(2)]·2CH(3)CN·2H(2)O, there are two Mn(III) and one Mn(II) atoms. The Mn(II) atom lies on an inversion center and the Mn(III)—Mn(II)—Mn(III) angle is therefore 180°, as required by crystallographic symmetry. The Mn(III...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212170/ https://www.ncbi.nlm.nih.gov/pubmed/22090872 http://dx.doi.org/10.1107/S1600536811027899 |
Sumario: | In the title complex, [Mn(II)Mn(III) (2)(C(11)H(13)NO(4))(2)(CH(3)CO(2))(4)(H(2)O)(2)]·2CH(3)CN·2H(2)O, there are two Mn(III) and one Mn(II) atoms. The Mn(II) atom lies on an inversion center and the Mn(III)—Mn(II)—Mn(III) angle is therefore 180°, as required by crystallographic symmetry. The Mn(III) and Mn(II) atoms are six-coordinated in a distorted octahedral geometry. In the crystal, complex molecules and solvent molecules are linked into a three-dimensional network by O—H⋯O and O—H⋯N hydrogen-bonding interactions. |
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