Tetra-μ(2)-acetato-diaqua­bis­(μ(2)-2-{[1,3-dihy­droxy-2-(oxidometh­yl)propan-2-yl]imino­meth­yl}phenolato)trimanganese(II,III) acetonitrile disolvate dihydrate

In the title complex, [Mn(II)Mn(III) (2)(C(11)H(13)NO(4))(2)(CH(3)CO(2))(4)(H(2)O)(2)]·2CH(3)CN·2H(2)O, there are two Mn(III) and one Mn(II) atoms. The Mn(II) atom lies on an inversion center and the Mn(III)—Mn(II)—Mn(III) angle is therefore 180°, as required by crystallographic symmetry. The Mn(III...

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Detalles Bibliográficos
Autores principales: Guo, Yuhua, Huang, Jianping, Huang, Yong, Wang, Junyue, Yu, Youzhu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212170/
https://www.ncbi.nlm.nih.gov/pubmed/22090872
http://dx.doi.org/10.1107/S1600536811027899
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author Guo, Yuhua
Huang, Jianping
Huang, Yong
Wang, Junyue
Yu, Youzhu
author_facet Guo, Yuhua
Huang, Jianping
Huang, Yong
Wang, Junyue
Yu, Youzhu
author_sort Guo, Yuhua
collection PubMed
description In the title complex, [Mn(II)Mn(III) (2)(C(11)H(13)NO(4))(2)(CH(3)CO(2))(4)(H(2)O)(2)]·2CH(3)CN·2H(2)O, there are two Mn(III) and one Mn(II) atoms. The Mn(II) atom lies on an inversion center and the Mn(III)—Mn(II)—Mn(III) angle is therefore 180°, as required by crystallographic symmetry. The Mn(III) and Mn(II) atoms are six-coordinated in a distorted octa­hedral geometry. In the crystal, complex mol­ecules and solvent mol­ecules are linked into a three-dimensional network by O—H⋯O and O—H⋯N hydrogen-bonding inter­actions.
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spelling pubmed-32121702011-11-16 Tetra-μ(2)-acetato-diaqua­bis­(μ(2)-2-{[1,3-dihy­droxy-2-(oxidometh­yl)propan-2-yl]imino­meth­yl}phenolato)trimanganese(II,III) acetonitrile disolvate dihydrate Guo, Yuhua Huang, Jianping Huang, Yong Wang, Junyue Yu, Youzhu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(II)Mn(III) (2)(C(11)H(13)NO(4))(2)(CH(3)CO(2))(4)(H(2)O)(2)]·2CH(3)CN·2H(2)O, there are two Mn(III) and one Mn(II) atoms. The Mn(II) atom lies on an inversion center and the Mn(III)—Mn(II)—Mn(III) angle is therefore 180°, as required by crystallographic symmetry. The Mn(III) and Mn(II) atoms are six-coordinated in a distorted octa­hedral geometry. In the crystal, complex mol­ecules and solvent mol­ecules are linked into a three-dimensional network by O—H⋯O and O—H⋯N hydrogen-bonding inter­actions. International Union of Crystallography 2011-07-16 /pmc/articles/PMC3212170/ /pubmed/22090872 http://dx.doi.org/10.1107/S1600536811027899 Text en © Guo et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guo, Yuhua
Huang, Jianping
Huang, Yong
Wang, Junyue
Yu, Youzhu
Tetra-μ(2)-acetato-diaqua­bis­(μ(2)-2-{[1,3-dihy­droxy-2-(oxidometh­yl)propan-2-yl]imino­meth­yl}phenolato)trimanganese(II,III) acetonitrile disolvate dihydrate
title Tetra-μ(2)-acetato-diaqua­bis­(μ(2)-2-{[1,3-dihy­droxy-2-(oxidometh­yl)propan-2-yl]imino­meth­yl}phenolato)trimanganese(II,III) acetonitrile disolvate dihydrate
title_full Tetra-μ(2)-acetato-diaqua­bis­(μ(2)-2-{[1,3-dihy­droxy-2-(oxidometh­yl)propan-2-yl]imino­meth­yl}phenolato)trimanganese(II,III) acetonitrile disolvate dihydrate
title_fullStr Tetra-μ(2)-acetato-diaqua­bis­(μ(2)-2-{[1,3-dihy­droxy-2-(oxidometh­yl)propan-2-yl]imino­meth­yl}phenolato)trimanganese(II,III) acetonitrile disolvate dihydrate
title_full_unstemmed Tetra-μ(2)-acetato-diaqua­bis­(μ(2)-2-{[1,3-dihy­droxy-2-(oxidometh­yl)propan-2-yl]imino­meth­yl}phenolato)trimanganese(II,III) acetonitrile disolvate dihydrate
title_short Tetra-μ(2)-acetato-diaqua­bis­(μ(2)-2-{[1,3-dihy­droxy-2-(oxidometh­yl)propan-2-yl]imino­meth­yl}phenolato)trimanganese(II,III) acetonitrile disolvate dihydrate
title_sort tetra-μ(2)-acetato-diaqua­bis­(μ(2)-2-{[1,3-dihy­droxy-2-(oxidometh­yl)propan-2-yl]imino­meth­yl}phenolato)trimanganese(ii,iii) acetonitrile disolvate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212170/
https://www.ncbi.nlm.nih.gov/pubmed/22090872
http://dx.doi.org/10.1107/S1600536811027899
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