catena-Poly[[diaqua­calcium]bis­[μ-2-(1,3-dioxoisoindolin-2-yl)acetato]-κ(3) O,O′:O;κ(3) O:O,O′]

In the title complex, [Ca(C(10)H(6)NO(4))(2)(H(2)O)(2)](n), the Ca(II) atom lies on a twofold rotation axis and adopts a dodeca­hedral geometry. The Ca(II) atom is octa­coordinated by two O atoms from two water mol­ecules and six O atoms from four acetate ligands. Each acetate acts as a tridentate l...

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Autores principales: Bhatti, Moazzam H., Yunus, Uzma, Saeed, Sohail, Shah, Syed Raza, Wong, Wing-Tak
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212173/
https://www.ncbi.nlm.nih.gov/pubmed/22090875
http://dx.doi.org/10.1107/S1600536811027851
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author Bhatti, Moazzam H.
Yunus, Uzma
Saeed, Sohail
Shah, Syed Raza
Wong, Wing-Tak
author_facet Bhatti, Moazzam H.
Yunus, Uzma
Saeed, Sohail
Shah, Syed Raza
Wong, Wing-Tak
author_sort Bhatti, Moazzam H.
collection PubMed
description In the title complex, [Ca(C(10)H(6)NO(4))(2)(H(2)O)(2)](n), the Ca(II) atom lies on a twofold rotation axis and adopts a dodeca­hedral geometry. The Ca(II) atom is octa­coordinated by two O atoms from two water mol­ecules and six O atoms from four acetate ligands. Each acetate acts as a tridentate ligand bridging two Ca(II) atoms, resulting in a chain running along the c axis. O—H⋯O and C—H⋯O hydrogen bonds connect the chains into a two-dimensional network parallel to [011]. π–π inter­actions between adjacent isoindoline-1,3-dione rings [centroid–centroid distance = 3.4096 (11) Å] further consolidate the structure. One of the carboxylate O atoms is disordered over two sites in a 0.879 (12):0.121 (12) ratio.
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spelling pubmed-32121732011-11-16 catena-Poly[[diaqua­calcium]bis­[μ-2-(1,3-dioxoisoindolin-2-yl)acetato]-κ(3) O,O′:O;κ(3) O:O,O′] Bhatti, Moazzam H. Yunus, Uzma Saeed, Sohail Shah, Syed Raza Wong, Wing-Tak Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ca(C(10)H(6)NO(4))(2)(H(2)O)(2)](n), the Ca(II) atom lies on a twofold rotation axis and adopts a dodeca­hedral geometry. The Ca(II) atom is octa­coordinated by two O atoms from two water mol­ecules and six O atoms from four acetate ligands. Each acetate acts as a tridentate ligand bridging two Ca(II) atoms, resulting in a chain running along the c axis. O—H⋯O and C—H⋯O hydrogen bonds connect the chains into a two-dimensional network parallel to [011]. π–π inter­actions between adjacent isoindoline-1,3-dione rings [centroid–centroid distance = 3.4096 (11) Å] further consolidate the structure. One of the carboxylate O atoms is disordered over two sites in a 0.879 (12):0.121 (12) ratio. International Union of Crystallography 2011-07-16 /pmc/articles/PMC3212173/ /pubmed/22090875 http://dx.doi.org/10.1107/S1600536811027851 Text en © Bhatti et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bhatti, Moazzam H.
Yunus, Uzma
Saeed, Sohail
Shah, Syed Raza
Wong, Wing-Tak
catena-Poly[[diaqua­calcium]bis­[μ-2-(1,3-dioxoisoindolin-2-yl)acetato]-κ(3) O,O′:O;κ(3) O:O,O′]
title catena-Poly[[diaqua­calcium]bis­[μ-2-(1,3-dioxoisoindolin-2-yl)acetato]-κ(3) O,O′:O;κ(3) O:O,O′]
title_full catena-Poly[[diaqua­calcium]bis­[μ-2-(1,3-dioxoisoindolin-2-yl)acetato]-κ(3) O,O′:O;κ(3) O:O,O′]
title_fullStr catena-Poly[[diaqua­calcium]bis­[μ-2-(1,3-dioxoisoindolin-2-yl)acetato]-κ(3) O,O′:O;κ(3) O:O,O′]
title_full_unstemmed catena-Poly[[diaqua­calcium]bis­[μ-2-(1,3-dioxoisoindolin-2-yl)acetato]-κ(3) O,O′:O;κ(3) O:O,O′]
title_short catena-Poly[[diaqua­calcium]bis­[μ-2-(1,3-dioxoisoindolin-2-yl)acetato]-κ(3) O,O′:O;κ(3) O:O,O′]
title_sort catena-poly[[diaqua­calcium]bis­[μ-2-(1,3-dioxoisoindolin-2-yl)acetato]-κ(3) o,o′:o;κ(3) o:o,o′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212173/
https://www.ncbi.nlm.nih.gov/pubmed/22090875
http://dx.doi.org/10.1107/S1600536811027851
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