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3,5-Diamino-4H-1,2,4-triazol-1-ium hydroxonium bis­(pyridine-2,6-di­carboxyl­ato)cobaltate(II) pyridine-2,6-dicarb­oxy­lic acid monohydrate

The asymmetric unit of the title complex, (C(2)H(6)N(5))(H(3)O)[Co(C(7)H(3)NO(4))(2)]·C(7)H(5)NO(4)·H(2)O, contains a Co(II) ion coordin­ated by four O atoms and two N atoms from two dipicolinate ligands in a disorted octa­hedral environment, a protonated triazole mol­ecule, a neutral pyridine-2,6-d...

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Detalles Bibliográficos
Autores principales: Yousuf, S., Johnson, A. S., Kazmi, S. A., Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212175/
https://www.ncbi.nlm.nih.gov/pubmed/22090877
http://dx.doi.org/10.1107/S1600536811027917
Descripción
Sumario:The asymmetric unit of the title complex, (C(2)H(6)N(5))(H(3)O)[Co(C(7)H(3)NO(4))(2)]·C(7)H(5)NO(4)·H(2)O, contains a Co(II) ion coordin­ated by four O atoms and two N atoms from two dipicolinate ligands in a disorted octa­hedral environment, a protonated triazole mol­ecule, a neutral pyridine-2,6-dicarb­oxy­lic acid mol­ecule, a hydroxonium ion and a solvent water mol­ecule. In the crystal, the components are linked into a three-dimensional framework by inter­molecular O—H⋯O, N—H⋯O and N—H⋯N and weak C—H⋯O hydrogen bonds. In addition, π–π stacking inter­actions with centroid–centroid distances in the range 3.4809 (7)–3.8145 (6) Å are observed.