3,5-Diamino-4H-1,2,4-triazol-1-ium hydroxonium bis­(pyridine-2,6-di­carboxyl­ato)cobaltate(II) pyridine-2,6-dicarb­oxy­lic acid monohydrate

The asymmetric unit of the title complex, (C(2)H(6)N(5))(H(3)O)[Co(C(7)H(3)NO(4))(2)]·C(7)H(5)NO(4)·H(2)O, contains a Co(II) ion coordin­ated by four O atoms and two N atoms from two dipicolinate ligands in a disorted octa­hedral environment, a protonated triazole mol­ecule, a neutral pyridine-2,6-d...

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Autores principales: Yousuf, S., Johnson, A. S., Kazmi, S. A., Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212175/
https://www.ncbi.nlm.nih.gov/pubmed/22090877
http://dx.doi.org/10.1107/S1600536811027917
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author Yousuf, S.
Johnson, A. S.
Kazmi, S. A.
Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Yousuf, S.
Johnson, A. S.
Kazmi, S. A.
Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Yousuf, S.
collection PubMed
description The asymmetric unit of the title complex, (C(2)H(6)N(5))(H(3)O)[Co(C(7)H(3)NO(4))(2)]·C(7)H(5)NO(4)·H(2)O, contains a Co(II) ion coordin­ated by four O atoms and two N atoms from two dipicolinate ligands in a disorted octa­hedral environment, a protonated triazole mol­ecule, a neutral pyridine-2,6-dicarb­oxy­lic acid mol­ecule, a hydroxonium ion and a solvent water mol­ecule. In the crystal, the components are linked into a three-dimensional framework by inter­molecular O—H⋯O, N—H⋯O and N—H⋯N and weak C—H⋯O hydrogen bonds. In addition, π–π stacking inter­actions with centroid–centroid distances in the range 3.4809 (7)–3.8145 (6) Å are observed.
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spelling pubmed-32121752011-11-16 3,5-Diamino-4H-1,2,4-triazol-1-ium hydroxonium bis­(pyridine-2,6-di­carboxyl­ato)cobaltate(II) pyridine-2,6-dicarb­oxy­lic acid monohydrate Yousuf, S. Johnson, A. S. Kazmi, S. A. Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, (C(2)H(6)N(5))(H(3)O)[Co(C(7)H(3)NO(4))(2)]·C(7)H(5)NO(4)·H(2)O, contains a Co(II) ion coordin­ated by four O atoms and two N atoms from two dipicolinate ligands in a disorted octa­hedral environment, a protonated triazole mol­ecule, a neutral pyridine-2,6-dicarb­oxy­lic acid mol­ecule, a hydroxonium ion and a solvent water mol­ecule. In the crystal, the components are linked into a three-dimensional framework by inter­molecular O—H⋯O, N—H⋯O and N—H⋯N and weak C—H⋯O hydrogen bonds. In addition, π–π stacking inter­actions with centroid–centroid distances in the range 3.4809 (7)–3.8145 (6) Å are observed. International Union of Crystallography 2011-07-16 /pmc/articles/PMC3212175/ /pubmed/22090877 http://dx.doi.org/10.1107/S1600536811027917 Text en © Yousuf et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yousuf, S.
Johnson, A. S.
Kazmi, S. A.
Hemamalini, Madhukar
Fun, Hoong-Kun
3,5-Diamino-4H-1,2,4-triazol-1-ium hydroxonium bis­(pyridine-2,6-di­carboxyl­ato)cobaltate(II) pyridine-2,6-dicarb­oxy­lic acid monohydrate
title 3,5-Diamino-4H-1,2,4-triazol-1-ium hydroxonium bis­(pyridine-2,6-di­carboxyl­ato)cobaltate(II) pyridine-2,6-dicarb­oxy­lic acid monohydrate
title_full 3,5-Diamino-4H-1,2,4-triazol-1-ium hydroxonium bis­(pyridine-2,6-di­carboxyl­ato)cobaltate(II) pyridine-2,6-dicarb­oxy­lic acid monohydrate
title_fullStr 3,5-Diamino-4H-1,2,4-triazol-1-ium hydroxonium bis­(pyridine-2,6-di­carboxyl­ato)cobaltate(II) pyridine-2,6-dicarb­oxy­lic acid monohydrate
title_full_unstemmed 3,5-Diamino-4H-1,2,4-triazol-1-ium hydroxonium bis­(pyridine-2,6-di­carboxyl­ato)cobaltate(II) pyridine-2,6-dicarb­oxy­lic acid monohydrate
title_short 3,5-Diamino-4H-1,2,4-triazol-1-ium hydroxonium bis­(pyridine-2,6-di­carboxyl­ato)cobaltate(II) pyridine-2,6-dicarb­oxy­lic acid monohydrate
title_sort 3,5-diamino-4h-1,2,4-triazol-1-ium hydroxonium bis­(pyridine-2,6-di­carboxyl­ato)cobaltate(ii) pyridine-2,6-dicarb­oxy­lic acid monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212175/
https://www.ncbi.nlm.nih.gov/pubmed/22090877
http://dx.doi.org/10.1107/S1600536811027917
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