Poly[[bis­(nitrato-κO)bis­(μ(4)-pyridine-4-carboxyl­ato)tetra­kis­(μ(3)-pyridine-4-carboxyl­ato)octa­silver(I)] hemihydrate]

In the title coordination polymer, {[Ag(8)(C(6)H(4)NO(2))(6)(NO(3))(2)]·0.5H(2)O}(n), two Ag(I) ions are two-coordinate within an AgN(2) set and six are three-coordinate within AgN(2)O and AgO(3) sets. The Ag—N and Ag—O distances are in the ranges 2.150 (5)–2.198 (5) and 2.142 (4)–2.702 (5) Å, respe...

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Detalles Bibliográficos
Autor principal: Meng, Zhao-Hui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212179/
https://www.ncbi.nlm.nih.gov/pubmed/22090881
http://dx.doi.org/10.1107/S1600536811028261
Descripción
Sumario:In the title coordination polymer, {[Ag(8)(C(6)H(4)NO(2))(6)(NO(3))(2)]·0.5H(2)O}(n), two Ag(I) ions are two-coordinate within an AgN(2) set and six are three-coordinate within AgN(2)O and AgO(3) sets. The Ag—N and Ag—O distances are in the ranges 2.150 (5)–2.198 (5) and 2.142 (4)–2.702 (5) Å, respectively. A two-dimensional coordination network is formed parallel to (100). The O atom of the disordered solvent water mol­ecule is located on an inversion center.

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