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Poly[[bis(nitrato-κO)bis(μ(4)-pyridine-4-carboxylato)tetrakis(μ(3)-pyridine-4-carboxylato)octasilver(I)] hemihydrate]
In the title coordination polymer, {[Ag(8)(C(6)H(4)NO(2))(6)(NO(3))(2)]·0.5H(2)O}(n), two Ag(I) ions are two-coordinate within an AgN(2) set and six are three-coordinate within AgN(2)O and AgO(3) sets. The Ag—N and Ag—O distances are in the ranges 2.150 (5)–2.198 (5) and 2.142 (4)–2.702 (5) Å, respe...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212179/ https://www.ncbi.nlm.nih.gov/pubmed/22090881 http://dx.doi.org/10.1107/S1600536811028261 |
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author | Meng, Zhao-Hui |
author_facet | Meng, Zhao-Hui |
author_sort | Meng, Zhao-Hui |
collection | PubMed |
description | In the title coordination polymer, {[Ag(8)(C(6)H(4)NO(2))(6)(NO(3))(2)]·0.5H(2)O}(n), two Ag(I) ions are two-coordinate within an AgN(2) set and six are three-coordinate within AgN(2)O and AgO(3) sets. The Ag—N and Ag—O distances are in the ranges 2.150 (5)–2.198 (5) and 2.142 (4)–2.702 (5) Å, respectively. A two-dimensional coordination network is formed parallel to (100). The O atom of the disordered solvent water molecule is located on an inversion center. |
format | Online Article Text |
id | pubmed-3212179 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32121792011-11-16 Poly[[bis(nitrato-κO)bis(μ(4)-pyridine-4-carboxylato)tetrakis(μ(3)-pyridine-4-carboxylato)octasilver(I)] hemihydrate] Meng, Zhao-Hui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[Ag(8)(C(6)H(4)NO(2))(6)(NO(3))(2)]·0.5H(2)O}(n), two Ag(I) ions are two-coordinate within an AgN(2) set and six are three-coordinate within AgN(2)O and AgO(3) sets. The Ag—N and Ag—O distances are in the ranges 2.150 (5)–2.198 (5) and 2.142 (4)–2.702 (5) Å, respectively. A two-dimensional coordination network is formed parallel to (100). The O atom of the disordered solvent water molecule is located on an inversion center. International Union of Crystallography 2011-07-23 /pmc/articles/PMC3212179/ /pubmed/22090881 http://dx.doi.org/10.1107/S1600536811028261 Text en © Zhao-Hui Meng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Meng, Zhao-Hui Poly[[bis(nitrato-κO)bis(μ(4)-pyridine-4-carboxylato)tetrakis(μ(3)-pyridine-4-carboxylato)octasilver(I)] hemihydrate] |
title | Poly[[bis(nitrato-κO)bis(μ(4)-pyridine-4-carboxylato)tetrakis(μ(3)-pyridine-4-carboxylato)octasilver(I)] hemihydrate] |
title_full | Poly[[bis(nitrato-κO)bis(μ(4)-pyridine-4-carboxylato)tetrakis(μ(3)-pyridine-4-carboxylato)octasilver(I)] hemihydrate] |
title_fullStr | Poly[[bis(nitrato-κO)bis(μ(4)-pyridine-4-carboxylato)tetrakis(μ(3)-pyridine-4-carboxylato)octasilver(I)] hemihydrate] |
title_full_unstemmed | Poly[[bis(nitrato-κO)bis(μ(4)-pyridine-4-carboxylato)tetrakis(μ(3)-pyridine-4-carboxylato)octasilver(I)] hemihydrate] |
title_short | Poly[[bis(nitrato-κO)bis(μ(4)-pyridine-4-carboxylato)tetrakis(μ(3)-pyridine-4-carboxylato)octasilver(I)] hemihydrate] |
title_sort | poly[[bis(nitrato-κo)bis(μ(4)-pyridine-4-carboxylato)tetrakis(μ(3)-pyridine-4-carboxylato)octasilver(i)] hemihydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212179/ https://www.ncbi.nlm.nih.gov/pubmed/22090881 http://dx.doi.org/10.1107/S1600536811028261 |
work_keys_str_mv | AT mengzhaohui polybisnitratokobism4pyridine4carboxylatotetrakism3pyridine4carboxylatooctasilverihemihydrate |