Cargando…

Bis(μ(2)-2-amino-5-nitro­benzoato)bis­(2-amino-5-nitro­benzoato)octa­butyldi-μ(3)-oxido-tetra­tin(IV)

In the title complex, [Sn(4)(C(4)H(9))(8)(C(7)H(5)N(2)O(4))(4)O(2)], all four Sn(IV) atoms are five-coordinated with distorted trigonal–bipyramidal SnC(2)O(3) geometries. Two Sn(IV) atoms are coordin­ated by two butyl groups, one benzoate O atom and two bridging O atoms, whereas the other two Sn(IV)...

Descripción completa

Detalles Bibliográficos
Autores principales: Win, Yip-Foo, Choong, Chen-Shang, Teoh, Siang-Guan, Yeap, Chin Sing, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212181/
https://www.ncbi.nlm.nih.gov/pubmed/22090883
http://dx.doi.org/10.1107/S1600536811028212
Descripción
Sumario:In the title complex, [Sn(4)(C(4)H(9))(8)(C(7)H(5)N(2)O(4))(4)O(2)], all four Sn(IV) atoms are five-coordinated with distorted trigonal–bipyramidal SnC(2)O(3) geometries. Two Sn(IV) atoms are coordin­ated by two butyl groups, one benzoate O atom and two bridging O atoms, whereas the other two Sn(IV) atoms are coordinated by two butyl groups, two benzoate O atoms and a bridging O atom. All the butyl groups are equatorial with respect to the SnO(3) trigonal plane. In the crystal, mol­ecules are linked into a two-dimensional layer parallel to the ab plane by inter­molecular N—H⋯O and C—H⋯O hydrogen bonds and further stabilized by a π–π inter­action [centroid–centroid distance = 3.6489 (11) Å]. Intra­molecular N—H⋯O and C—H⋯O hydrogen bonds stabilize the mol­ecular structure. Two of the butyl groups are each disordered over two sets of sites with site-occupancy ratios of 0.510 (4):0.490 (4) and 0.860 (5):0.140 (5).