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Bis(μ(2)-2-amino-5-nitro­benzoato)bis­(2-amino-5-nitro­benzoato)octa­butyldi-μ(3)-oxido-tetra­tin(IV)

In the title complex, [Sn(4)(C(4)H(9))(8)(C(7)H(5)N(2)O(4))(4)O(2)], all four Sn(IV) atoms are five-coordinated with distorted trigonal–bipyramidal SnC(2)O(3) geometries. Two Sn(IV) atoms are coordin­ated by two butyl groups, one benzoate O atom and two bridging O atoms, whereas the other two Sn(IV)...

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Autores principales: Win, Yip-Foo, Choong, Chen-Shang, Teoh, Siang-Guan, Yeap, Chin Sing, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212181/
https://www.ncbi.nlm.nih.gov/pubmed/22090883
http://dx.doi.org/10.1107/S1600536811028212
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author Win, Yip-Foo
Choong, Chen-Shang
Teoh, Siang-Guan
Yeap, Chin Sing
Fun, Hoong-Kun
author_facet Win, Yip-Foo
Choong, Chen-Shang
Teoh, Siang-Guan
Yeap, Chin Sing
Fun, Hoong-Kun
author_sort Win, Yip-Foo
collection PubMed
description In the title complex, [Sn(4)(C(4)H(9))(8)(C(7)H(5)N(2)O(4))(4)O(2)], all four Sn(IV) atoms are five-coordinated with distorted trigonal–bipyramidal SnC(2)O(3) geometries. Two Sn(IV) atoms are coordin­ated by two butyl groups, one benzoate O atom and two bridging O atoms, whereas the other two Sn(IV) atoms are coordinated by two butyl groups, two benzoate O atoms and a bridging O atom. All the butyl groups are equatorial with respect to the SnO(3) trigonal plane. In the crystal, mol­ecules are linked into a two-dimensional layer parallel to the ab plane by inter­molecular N—H⋯O and C—H⋯O hydrogen bonds and further stabilized by a π–π inter­action [centroid–centroid distance = 3.6489 (11) Å]. Intra­molecular N—H⋯O and C—H⋯O hydrogen bonds stabilize the mol­ecular structure. Two of the butyl groups are each disordered over two sets of sites with site-occupancy ratios of 0.510 (4):0.490 (4) and 0.860 (5):0.140 (5).
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spelling pubmed-32121812011-11-16 Bis(μ(2)-2-amino-5-nitro­benzoato)bis­(2-amino-5-nitro­benzoato)octa­butyldi-μ(3)-oxido-tetra­tin(IV) Win, Yip-Foo Choong, Chen-Shang Teoh, Siang-Guan Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Sn(4)(C(4)H(9))(8)(C(7)H(5)N(2)O(4))(4)O(2)], all four Sn(IV) atoms are five-coordinated with distorted trigonal–bipyramidal SnC(2)O(3) geometries. Two Sn(IV) atoms are coordin­ated by two butyl groups, one benzoate O atom and two bridging O atoms, whereas the other two Sn(IV) atoms are coordinated by two butyl groups, two benzoate O atoms and a bridging O atom. All the butyl groups are equatorial with respect to the SnO(3) trigonal plane. In the crystal, mol­ecules are linked into a two-dimensional layer parallel to the ab plane by inter­molecular N—H⋯O and C—H⋯O hydrogen bonds and further stabilized by a π–π inter­action [centroid–centroid distance = 3.6489 (11) Å]. Intra­molecular N—H⋯O and C—H⋯O hydrogen bonds stabilize the mol­ecular structure. Two of the butyl groups are each disordered over two sets of sites with site-occupancy ratios of 0.510 (4):0.490 (4) and 0.860 (5):0.140 (5). International Union of Crystallography 2011-07-23 /pmc/articles/PMC3212181/ /pubmed/22090883 http://dx.doi.org/10.1107/S1600536811028212 Text en © Win et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Win, Yip-Foo
Choong, Chen-Shang
Teoh, Siang-Guan
Yeap, Chin Sing
Fun, Hoong-Kun
Bis(μ(2)-2-amino-5-nitro­benzoato)bis­(2-amino-5-nitro­benzoato)octa­butyldi-μ(3)-oxido-tetra­tin(IV)
title Bis(μ(2)-2-amino-5-nitro­benzoato)bis­(2-amino-5-nitro­benzoato)octa­butyldi-μ(3)-oxido-tetra­tin(IV)
title_full Bis(μ(2)-2-amino-5-nitro­benzoato)bis­(2-amino-5-nitro­benzoato)octa­butyldi-μ(3)-oxido-tetra­tin(IV)
title_fullStr Bis(μ(2)-2-amino-5-nitro­benzoato)bis­(2-amino-5-nitro­benzoato)octa­butyldi-μ(3)-oxido-tetra­tin(IV)
title_full_unstemmed Bis(μ(2)-2-amino-5-nitro­benzoato)bis­(2-amino-5-nitro­benzoato)octa­butyldi-μ(3)-oxido-tetra­tin(IV)
title_short Bis(μ(2)-2-amino-5-nitro­benzoato)bis­(2-amino-5-nitro­benzoato)octa­butyldi-μ(3)-oxido-tetra­tin(IV)
title_sort bis(μ(2)-2-amino-5-nitro­benzoato)bis­(2-amino-5-nitro­benzoato)octa­butyldi-μ(3)-oxido-tetra­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212181/
https://www.ncbi.nlm.nih.gov/pubmed/22090883
http://dx.doi.org/10.1107/S1600536811028212
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