3,3′-Dimethyl-1,1′-(propane-1,3-di­yl)diimidazol-1-ium bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)nickelate(II)

In the title compound, (C(11)H(18)N(4))[Ni(C(4)N(2)S(2))(2)], the asymmetric contains one half-complex, with the cation placed on a twofold axis and the anion located on an inversion center. The Ni(II) ion in the anion is coordinated by four S atoms of two maleonitrile­dithiol­ate ligands, and exhib...

Descripción completa

Detalles Bibliográficos
Autores principales: Yu, Shan-Shan, Duan, Hai-Bao, Ren, Xiao-Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212183/
https://www.ncbi.nlm.nih.gov/pubmed/22090885
http://dx.doi.org/10.1107/S1600536811027693
Descripción
Sumario:In the title compound, (C(11)H(18)N(4))[Ni(C(4)N(2)S(2))(2)], the asymmetric contains one half-complex, with the cation placed on a twofold axis and the anion located on an inversion center. The Ni(II) ion in the anion is coordinated by four S atoms of two maleonitrile­dithiol­ate ligands, and exhibits the expected square-planar coordination geometry.

Ejemplares similares