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Bis(1H-imidazole-κN (3))bis(2-methylbenzoato-κO)bis(2-methylbenzoic acid-κO)copper(II)
The structure of the title compound, [Cu(C(8)H(7)O(2))(2)(C(3)H(4)N(2))(2)(C(8)H(8)O(2))(2)], consists of centrosymmetric monomeric units, in which the Cu(II) atom has a tetragonally distorted octahedral coordination involving two imidazole N atoms and two carboxylate O atoms in the square plane...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212187/ https://www.ncbi.nlm.nih.gov/pubmed/22090889 http://dx.doi.org/10.1107/S160053681102839X |
Sumario: | The structure of the title compound, [Cu(C(8)H(7)O(2))(2)(C(3)H(4)N(2))(2)(C(8)H(8)O(2))(2)], consists of centrosymmetric monomeric units, in which the Cu(II) atom has a tetragonally distorted octahedral coordination involving two imidazole N atoms and two carboxylate O atoms in the square plane [Cu—N = 1.964 (3) and Cu—O = 1.960 (2) Å] and 2-methylbenzoic acid O atoms in axial sites [Cu—O = 2.753 (3) Å]. Within the complex, the carboxylic acid forms intramolecular O—H⋯O hydrogen bonds, while the molecules are assembled through N—H⋯O(carboxyl) hydrogen bonds into chains extending along the a-axis direction. These chains are further linked by weak π–π interactions [centroid–centroid separation = 3.930 (2) Å]. |
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