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Bis(1H-imidazole-κN (3))bis­(2-methyl­benzoato-κO)bis­(2-methyl­benzoic acid-κO)copper(II)

The structure of the title compound, [Cu(C(8)H(7)O(2))(2)(C(3)H(4)N(2))(2)(C(8)H(8)O(2))(2)], consists of centrosymmetric monomeric units, in which the Cu(II) atom has a tetra­gonally distorted octa­hedral coordination involving two imidazole N atoms and two carboxyl­ate O atoms in the square plane...

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Autores principales: Ni, Sheng-Liang, Zhao, Ming-Xing, Ge, Hai-Xia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212187/
https://www.ncbi.nlm.nih.gov/pubmed/22090889
http://dx.doi.org/10.1107/S160053681102839X
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author Ni, Sheng-Liang
Zhao, Ming-Xing
Ge, Hai-Xia
author_facet Ni, Sheng-Liang
Zhao, Ming-Xing
Ge, Hai-Xia
author_sort Ni, Sheng-Liang
collection PubMed
description The structure of the title compound, [Cu(C(8)H(7)O(2))(2)(C(3)H(4)N(2))(2)(C(8)H(8)O(2))(2)], consists of centrosymmetric monomeric units, in which the Cu(II) atom has a tetra­gonally distorted octa­hedral coordination involving two imidazole N atoms and two carboxyl­ate O atoms in the square plane [Cu—N = 1.964 (3) and Cu—O = 1.960 (2) Å] and 2-methyl­benzoic acid O atoms in axial sites [Cu—O = 2.753 (3) Å]. Within the complex, the carb­oxy­lic acid forms intra­molecular O—H⋯O hydrogen bonds, while the mol­ecules are assembled through N—H⋯O(carbox­yl) hydrogen bonds into chains extending along the a-axis direction. These chains are further linked by weak π–π inter­actions [centroid–centroid separation = 3.930 (2) Å].
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spelling pubmed-32121872011-11-16 Bis(1H-imidazole-κN (3))bis­(2-methyl­benzoato-κO)bis­(2-methyl­benzoic acid-κO)copper(II) Ni, Sheng-Liang Zhao, Ming-Xing Ge, Hai-Xia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Cu(C(8)H(7)O(2))(2)(C(3)H(4)N(2))(2)(C(8)H(8)O(2))(2)], consists of centrosymmetric monomeric units, in which the Cu(II) atom has a tetra­gonally distorted octa­hedral coordination involving two imidazole N atoms and two carboxyl­ate O atoms in the square plane [Cu—N = 1.964 (3) and Cu—O = 1.960 (2) Å] and 2-methyl­benzoic acid O atoms in axial sites [Cu—O = 2.753 (3) Å]. Within the complex, the carb­oxy­lic acid forms intra­molecular O—H⋯O hydrogen bonds, while the mol­ecules are assembled through N—H⋯O(carbox­yl) hydrogen bonds into chains extending along the a-axis direction. These chains are further linked by weak π–π inter­actions [centroid–centroid separation = 3.930 (2) Å]. International Union of Crystallography 2011-07-23 /pmc/articles/PMC3212187/ /pubmed/22090889 http://dx.doi.org/10.1107/S160053681102839X Text en © Ni et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ni, Sheng-Liang
Zhao, Ming-Xing
Ge, Hai-Xia
Bis(1H-imidazole-κN (3))bis­(2-methyl­benzoato-κO)bis­(2-methyl­benzoic acid-κO)copper(II)
title Bis(1H-imidazole-κN (3))bis­(2-methyl­benzoato-κO)bis­(2-methyl­benzoic acid-κO)copper(II)
title_full Bis(1H-imidazole-κN (3))bis­(2-methyl­benzoato-κO)bis­(2-methyl­benzoic acid-κO)copper(II)
title_fullStr Bis(1H-imidazole-κN (3))bis­(2-methyl­benzoato-κO)bis­(2-methyl­benzoic acid-κO)copper(II)
title_full_unstemmed Bis(1H-imidazole-κN (3))bis­(2-methyl­benzoato-κO)bis­(2-methyl­benzoic acid-κO)copper(II)
title_short Bis(1H-imidazole-κN (3))bis­(2-methyl­benzoato-κO)bis­(2-methyl­benzoic acid-κO)copper(II)
title_sort bis(1h-imidazole-κn (3))bis­(2-methyl­benzoato-κo)bis­(2-methyl­benzoic acid-κo)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212187/
https://www.ncbi.nlm.nih.gov/pubmed/22090889
http://dx.doi.org/10.1107/S160053681102839X
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