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Bis(1H-imidazole-κN (3))bis(2-methylbenzoato-κO)bis(2-methylbenzoic acid-κO)copper(II)
The structure of the title compound, [Cu(C(8)H(7)O(2))(2)(C(3)H(4)N(2))(2)(C(8)H(8)O(2))(2)], consists of centrosymmetric monomeric units, in which the Cu(II) atom has a tetragonally distorted octahedral coordination involving two imidazole N atoms and two carboxylate O atoms in the square plane...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212187/ https://www.ncbi.nlm.nih.gov/pubmed/22090889 http://dx.doi.org/10.1107/S160053681102839X |
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author | Ni, Sheng-Liang Zhao, Ming-Xing Ge, Hai-Xia |
author_facet | Ni, Sheng-Liang Zhao, Ming-Xing Ge, Hai-Xia |
author_sort | Ni, Sheng-Liang |
collection | PubMed |
description | The structure of the title compound, [Cu(C(8)H(7)O(2))(2)(C(3)H(4)N(2))(2)(C(8)H(8)O(2))(2)], consists of centrosymmetric monomeric units, in which the Cu(II) atom has a tetragonally distorted octahedral coordination involving two imidazole N atoms and two carboxylate O atoms in the square plane [Cu—N = 1.964 (3) and Cu—O = 1.960 (2) Å] and 2-methylbenzoic acid O atoms in axial sites [Cu—O = 2.753 (3) Å]. Within the complex, the carboxylic acid forms intramolecular O—H⋯O hydrogen bonds, while the molecules are assembled through N—H⋯O(carboxyl) hydrogen bonds into chains extending along the a-axis direction. These chains are further linked by weak π–π interactions [centroid–centroid separation = 3.930 (2) Å]. |
format | Online Article Text |
id | pubmed-3212187 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32121872011-11-16 Bis(1H-imidazole-κN (3))bis(2-methylbenzoato-κO)bis(2-methylbenzoic acid-κO)copper(II) Ni, Sheng-Liang Zhao, Ming-Xing Ge, Hai-Xia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Cu(C(8)H(7)O(2))(2)(C(3)H(4)N(2))(2)(C(8)H(8)O(2))(2)], consists of centrosymmetric monomeric units, in which the Cu(II) atom has a tetragonally distorted octahedral coordination involving two imidazole N atoms and two carboxylate O atoms in the square plane [Cu—N = 1.964 (3) and Cu—O = 1.960 (2) Å] and 2-methylbenzoic acid O atoms in axial sites [Cu—O = 2.753 (3) Å]. Within the complex, the carboxylic acid forms intramolecular O—H⋯O hydrogen bonds, while the molecules are assembled through N—H⋯O(carboxyl) hydrogen bonds into chains extending along the a-axis direction. These chains are further linked by weak π–π interactions [centroid–centroid separation = 3.930 (2) Å]. International Union of Crystallography 2011-07-23 /pmc/articles/PMC3212187/ /pubmed/22090889 http://dx.doi.org/10.1107/S160053681102839X Text en © Ni et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ni, Sheng-Liang Zhao, Ming-Xing Ge, Hai-Xia Bis(1H-imidazole-κN (3))bis(2-methylbenzoato-κO)bis(2-methylbenzoic acid-κO)copper(II) |
title | Bis(1H-imidazole-κN
(3))bis(2-methylbenzoato-κO)bis(2-methylbenzoic acid-κO)copper(II) |
title_full | Bis(1H-imidazole-κN
(3))bis(2-methylbenzoato-κO)bis(2-methylbenzoic acid-κO)copper(II) |
title_fullStr | Bis(1H-imidazole-κN
(3))bis(2-methylbenzoato-κO)bis(2-methylbenzoic acid-κO)copper(II) |
title_full_unstemmed | Bis(1H-imidazole-κN
(3))bis(2-methylbenzoato-κO)bis(2-methylbenzoic acid-κO)copper(II) |
title_short | Bis(1H-imidazole-κN
(3))bis(2-methylbenzoato-κO)bis(2-methylbenzoic acid-κO)copper(II) |
title_sort | bis(1h-imidazole-κn
(3))bis(2-methylbenzoato-κo)bis(2-methylbenzoic acid-κo)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212187/ https://www.ncbi.nlm.nih.gov/pubmed/22090889 http://dx.doi.org/10.1107/S160053681102839X |
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