Bis(acetonitrile-κN)diaqua­bis­(perchlorato-κO)copper(II)

In the title compound, [Cu(ClO(4))(2)(CH(3)CN)(2)(H(2)O)(2)], the Cu(2+) ion, located on a special position (site symmetry [Image: see text]), is coordinated by six monodentate ligands, viz. an N-coordin­ated acetonitrile, a perchlorate anion and a water mol­ecule, and their symmetry-related counter...

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Detalles Bibliográficos
Autores principales: Tafeenko, Viktor A., Gurskiy, Stanislav I., Aslanov, Leonid A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212188/
https://www.ncbi.nlm.nih.gov/pubmed/22090890
http://dx.doi.org/10.1107/S1600536811027309
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author Tafeenko, Viktor A.
Gurskiy, Stanislav I.
Aslanov, Leonid A.
author_facet Tafeenko, Viktor A.
Gurskiy, Stanislav I.
Aslanov, Leonid A.
author_sort Tafeenko, Viktor A.
collection PubMed
description In the title compound, [Cu(ClO(4))(2)(CH(3)CN)(2)(H(2)O)(2)], the Cu(2+) ion, located on a special position (site symmetry [Image: see text]), is coordinated by six monodentate ligands, viz. an N-coordin­ated acetonitrile, a perchlorate anion and a water mol­ecule, and their symmetry-related counterparts. The perchlorate anion is disordered over two sets of sites with occupancies of 0.53 (2) and 0.47 (2). The crystal structure is stabilized by O—H⋯O hydrogen bonds involving the perchlorate ion and aqua H atoms.
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spelling pubmed-32121882011-11-16 Bis(acetonitrile-κN)diaqua­bis­(perchlorato-κO)copper(II) Tafeenko, Viktor A. Gurskiy, Stanislav I. Aslanov, Leonid A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(ClO(4))(2)(CH(3)CN)(2)(H(2)O)(2)], the Cu(2+) ion, located on a special position (site symmetry [Image: see text]), is coordinated by six monodentate ligands, viz. an N-coordin­ated acetonitrile, a perchlorate anion and a water mol­ecule, and their symmetry-related counterparts. The perchlorate anion is disordered over two sets of sites with occupancies of 0.53 (2) and 0.47 (2). The crystal structure is stabilized by O—H⋯O hydrogen bonds involving the perchlorate ion and aqua H atoms. International Union of Crystallography 2011-07-23 /pmc/articles/PMC3212188/ /pubmed/22090890 http://dx.doi.org/10.1107/S1600536811027309 Text en © Tafeenko et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tafeenko, Viktor A.
Gurskiy, Stanislav I.
Aslanov, Leonid A.
Bis(acetonitrile-κN)diaqua­bis­(perchlorato-κO)copper(II)
title Bis(acetonitrile-κN)diaqua­bis­(perchlorato-κO)copper(II)
title_full Bis(acetonitrile-κN)diaqua­bis­(perchlorato-κO)copper(II)
title_fullStr Bis(acetonitrile-κN)diaqua­bis­(perchlorato-κO)copper(II)
title_full_unstemmed Bis(acetonitrile-κN)diaqua­bis­(perchlorato-κO)copper(II)
title_short Bis(acetonitrile-κN)diaqua­bis­(perchlorato-κO)copper(II)
title_sort bis(acetonitrile-κn)diaqua­bis­(perchlorato-κo)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212188/
https://www.ncbi.nlm.nih.gov/pubmed/22090890
http://dx.doi.org/10.1107/S1600536811027309
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