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{μ-6,6′-Dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-1κ(4) O (6),O (1),O (1′),O (6′);2κ(4) O (1),N,N′,O (1′)}(methanol-1κO)(tetrafluoridoborato-1κ(2) F,F′)-2-copper(II)-1-sodium
In the dinuclear salen-type title complex, [CuNa(BF(4))(C(18)H(18)N(2)O(4))(CH(3)OH)], the Cu(II) atom is chelated by two O atoms and two N atoms of the deprotonated Schiff base in a square-planar geometry. The Na atom is seven-coordinate as it is linked to four O atoms of the same Schiff base ligan...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212189/ https://www.ncbi.nlm.nih.gov/pubmed/22090891 http://dx.doi.org/10.1107/S160053681102842X |
| _version_ | 1782215938640183296 |
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| author | Gao, Ting Yang, Yu Gao, Po Zhang, Ju-Wen Yang, Jing-Lin |
| author_facet | Gao, Ting Yang, Yu Gao, Po Zhang, Ju-Wen Yang, Jing-Lin |
| author_sort | Gao, Ting |
| collection | PubMed |
| description | In the dinuclear salen-type title complex, [CuNa(BF(4))(C(18)H(18)N(2)O(4))(CH(3)OH)], the Cu(II) atom is chelated by two O atoms and two N atoms of the deprotonated Schiff base in a square-planar geometry. The Na atom is seven-coordinate as it is linked to four O atoms of the same Schiff base ligand, one O atom of the methanol and two tetrafluoridoborate F atoms. The remaining two F atoms of the anion are disordered over two sites in a 0.598 (18):0.402 (18) ratio. |
| format | Online Article Text |
| id | pubmed-3212189 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32121892011-11-16 {μ-6,6′-Dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-1κ(4) O (6),O (1),O (1′),O (6′);2κ(4) O (1),N,N′,O (1′)}(methanol-1κO)(tetrafluoridoborato-1κ(2) F,F′)-2-copper(II)-1-sodium Gao, Ting Yang, Yu Gao, Po Zhang, Ju-Wen Yang, Jing-Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the dinuclear salen-type title complex, [CuNa(BF(4))(C(18)H(18)N(2)O(4))(CH(3)OH)], the Cu(II) atom is chelated by two O atoms and two N atoms of the deprotonated Schiff base in a square-planar geometry. The Na atom is seven-coordinate as it is linked to four O atoms of the same Schiff base ligand, one O atom of the methanol and two tetrafluoridoborate F atoms. The remaining two F atoms of the anion are disordered over two sites in a 0.598 (18):0.402 (18) ratio. International Union of Crystallography 2011-07-23 /pmc/articles/PMC3212189/ /pubmed/22090891 http://dx.doi.org/10.1107/S160053681102842X Text en © Gao et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Gao, Ting Yang, Yu Gao, Po Zhang, Ju-Wen Yang, Jing-Lin {μ-6,6′-Dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-1κ(4) O (6),O (1),O (1′),O (6′);2κ(4) O (1),N,N′,O (1′)}(methanol-1κO)(tetrafluoridoborato-1κ(2) F,F′)-2-copper(II)-1-sodium |
| title | {μ-6,6′-Dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-1κ(4)
O
(6),O
(1),O
(1′),O
(6′);2κ(4)
O
(1),N,N′,O
(1′)}(methanol-1κO)(tetrafluoridoborato-1κ(2)
F,F′)-2-copper(II)-1-sodium |
| title_full | {μ-6,6′-Dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-1κ(4)
O
(6),O
(1),O
(1′),O
(6′);2κ(4)
O
(1),N,N′,O
(1′)}(methanol-1κO)(tetrafluoridoborato-1κ(2)
F,F′)-2-copper(II)-1-sodium |
| title_fullStr | {μ-6,6′-Dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-1κ(4)
O
(6),O
(1),O
(1′),O
(6′);2κ(4)
O
(1),N,N′,O
(1′)}(methanol-1κO)(tetrafluoridoborato-1κ(2)
F,F′)-2-copper(II)-1-sodium |
| title_full_unstemmed | {μ-6,6′-Dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-1κ(4)
O
(6),O
(1),O
(1′),O
(6′);2κ(4)
O
(1),N,N′,O
(1′)}(methanol-1κO)(tetrafluoridoborato-1κ(2)
F,F′)-2-copper(II)-1-sodium |
| title_short | {μ-6,6′-Dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-1κ(4)
O
(6),O
(1),O
(1′),O
(6′);2κ(4)
O
(1),N,N′,O
(1′)}(methanol-1κO)(tetrafluoridoborato-1κ(2)
F,F′)-2-copper(II)-1-sodium |
| title_sort | {μ-6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-1κ(4)
o
(6),o
(1),o
(1′),o
(6′);2κ(4)
o
(1),n,n′,o
(1′)}(methanol-1κo)(tetrafluoridoborato-1κ(2)
f,f′)-2-copper(ii)-1-sodium |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212189/ https://www.ncbi.nlm.nih.gov/pubmed/22090891 http://dx.doi.org/10.1107/S160053681102842X |
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