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Poly[[μ-aqua-tetraaquabis(μ-2-hydroxy-4-oxocyclobut-1-ene-1,3-diolato)strontium] hemihydrate]
In the title coordination polymer, {[Sr(C(4)HO(4))(2)(H(2)O)(5)]·0.5H(2)O}(n), the Sr(2+) ion is coordinated by three monodentate hydrogensquarate (hsq) anions and six aqua ligands in a distorted SrO(9) monocapped square-antiprismatic geometry. The hsq anions and water molecules bridge the metal i...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212191/ https://www.ncbi.nlm.nih.gov/pubmed/22090893 http://dx.doi.org/10.1107/S1600536811028704 |
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author | Bouhali, Amira Trifa, Chahrazed Bouacida, Sofiane Boudaren, Chaouki Bataille, Thierry |
author_facet | Bouhali, Amira Trifa, Chahrazed Bouacida, Sofiane Boudaren, Chaouki Bataille, Thierry |
author_sort | Bouhali, Amira |
collection | PubMed |
description | In the title coordination polymer, {[Sr(C(4)HO(4))(2)(H(2)O)(5)]·0.5H(2)O}(n), the Sr(2+) ion is coordinated by three monodentate hydrogensquarate (hsq) anions and six aqua ligands in a distorted SrO(9) monocapped square-antiprismatic geometry. The hsq anions and water molecules bridge the metal ions into infinite sheets lying parallel to (100). The O atom of the uncoordinated water molecule lies on a crystallographic twofold axis. The packing is stabilized by numerous O—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-3212191 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32121912011-11-16 Poly[[μ-aqua-tetraaquabis(μ-2-hydroxy-4-oxocyclobut-1-ene-1,3-diolato)strontium] hemihydrate] Bouhali, Amira Trifa, Chahrazed Bouacida, Sofiane Boudaren, Chaouki Bataille, Thierry Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[Sr(C(4)HO(4))(2)(H(2)O)(5)]·0.5H(2)O}(n), the Sr(2+) ion is coordinated by three monodentate hydrogensquarate (hsq) anions and six aqua ligands in a distorted SrO(9) monocapped square-antiprismatic geometry. The hsq anions and water molecules bridge the metal ions into infinite sheets lying parallel to (100). The O atom of the uncoordinated water molecule lies on a crystallographic twofold axis. The packing is stabilized by numerous O—H⋯O hydrogen bonds. International Union of Crystallography 2011-07-23 /pmc/articles/PMC3212191/ /pubmed/22090893 http://dx.doi.org/10.1107/S1600536811028704 Text en © Bouhali et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Bouhali, Amira Trifa, Chahrazed Bouacida, Sofiane Boudaren, Chaouki Bataille, Thierry Poly[[μ-aqua-tetraaquabis(μ-2-hydroxy-4-oxocyclobut-1-ene-1,3-diolato)strontium] hemihydrate] |
title | Poly[[μ-aqua-tetraaquabis(μ-2-hydroxy-4-oxocyclobut-1-ene-1,3-diolato)strontium] hemihydrate] |
title_full | Poly[[μ-aqua-tetraaquabis(μ-2-hydroxy-4-oxocyclobut-1-ene-1,3-diolato)strontium] hemihydrate] |
title_fullStr | Poly[[μ-aqua-tetraaquabis(μ-2-hydroxy-4-oxocyclobut-1-ene-1,3-diolato)strontium] hemihydrate] |
title_full_unstemmed | Poly[[μ-aqua-tetraaquabis(μ-2-hydroxy-4-oxocyclobut-1-ene-1,3-diolato)strontium] hemihydrate] |
title_short | Poly[[μ-aqua-tetraaquabis(μ-2-hydroxy-4-oxocyclobut-1-ene-1,3-diolato)strontium] hemihydrate] |
title_sort | poly[[μ-aqua-tetraaquabis(μ-2-hydroxy-4-oxocyclobut-1-ene-1,3-diolato)strontium] hemihydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212191/ https://www.ncbi.nlm.nih.gov/pubmed/22090893 http://dx.doi.org/10.1107/S1600536811028704 |
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