{N′-[(E)-1-(5-Bromo-2-oxidophen­yl)ethyl­idene-κO]-4-methyl­benzohydrazidato-κ(2) N′,O}(pyridine-κN)nickel(II)

The central Ni(II) atom in the title complex, [Ni(C(16)H(13)BrN(2)O(2))(C(5)H(5)N)], is in a square-planar trans-N(2)O(2) environment defined by the NO(2) donor atoms of the tridentate hydrazone ligand and the monodentate pyridine ligand. The pyridine mol­ecule forms a dihedral angle of 9.99 (11)° w...

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Detalles Bibliográficos
Autores principales: Zheng, Chang-Zheng, Wang, Liang, Liu, Juan, Wang, Yu-Jie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212192/
https://www.ncbi.nlm.nih.gov/pubmed/22090894
http://dx.doi.org/10.1107/S1600536811029114
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author Zheng, Chang-Zheng
Wang, Liang
Liu, Juan
Wang, Yu-Jie
author_facet Zheng, Chang-Zheng
Wang, Liang
Liu, Juan
Wang, Yu-Jie
author_sort Zheng, Chang-Zheng
collection PubMed
description The central Ni(II) atom in the title complex, [Ni(C(16)H(13)BrN(2)O(2))(C(5)H(5)N)], is in a square-planar trans-N(2)O(2) environment defined by the NO(2) donor atoms of the tridentate hydrazone ligand and the monodentate pyridine ligand. The pyridine mol­ecule forms a dihedral angle of 9.99 (11)° with the least-squares plane through the NiN(2)O(2) atoms.
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spelling pubmed-32121922011-11-16 {N′-[(E)-1-(5-Bromo-2-oxidophen­yl)ethyl­idene-κO]-4-methyl­benzohydrazidato-κ(2) N′,O}(pyridine-κN)nickel(II) Zheng, Chang-Zheng Wang, Liang Liu, Juan Wang, Yu-Jie Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The central Ni(II) atom in the title complex, [Ni(C(16)H(13)BrN(2)O(2))(C(5)H(5)N)], is in a square-planar trans-N(2)O(2) environment defined by the NO(2) donor atoms of the tridentate hydrazone ligand and the monodentate pyridine ligand. The pyridine mol­ecule forms a dihedral angle of 9.99 (11)° with the least-squares plane through the NiN(2)O(2) atoms. International Union of Crystallography 2011-07-23 /pmc/articles/PMC3212192/ /pubmed/22090894 http://dx.doi.org/10.1107/S1600536811029114 Text en © Zheng et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zheng, Chang-Zheng
Wang, Liang
Liu, Juan
Wang, Yu-Jie
{N′-[(E)-1-(5-Bromo-2-oxidophen­yl)ethyl­idene-κO]-4-methyl­benzohydrazidato-κ(2) N′,O}(pyridine-κN)nickel(II)
title {N′-[(E)-1-(5-Bromo-2-oxidophen­yl)ethyl­idene-κO]-4-methyl­benzohydrazidato-κ(2) N′,O}(pyridine-κN)nickel(II)
title_full {N′-[(E)-1-(5-Bromo-2-oxidophen­yl)ethyl­idene-κO]-4-methyl­benzohydrazidato-κ(2) N′,O}(pyridine-κN)nickel(II)
title_fullStr {N′-[(E)-1-(5-Bromo-2-oxidophen­yl)ethyl­idene-κO]-4-methyl­benzohydrazidato-κ(2) N′,O}(pyridine-κN)nickel(II)
title_full_unstemmed {N′-[(E)-1-(5-Bromo-2-oxidophen­yl)ethyl­idene-κO]-4-methyl­benzohydrazidato-κ(2) N′,O}(pyridine-κN)nickel(II)
title_short {N′-[(E)-1-(5-Bromo-2-oxidophen­yl)ethyl­idene-κO]-4-methyl­benzohydrazidato-κ(2) N′,O}(pyridine-κN)nickel(II)
title_sort {n′-[(e)-1-(5-bromo-2-oxidophen­yl)ethyl­idene-κo]-4-methyl­benzohydrazidato-κ(2) n′,o}(pyridine-κn)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212192/
https://www.ncbi.nlm.nih.gov/pubmed/22090894
http://dx.doi.org/10.1107/S1600536811029114
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