(Acetonitrile-κN)[2-(diphenylphosphan­yl)ethanamine-κ(2) N,P][(1,2,3,4,5-η)-1,2,3,4,5-pentamethylcyclopentadienyl]iron(II) hexafluoridophosphate tetrahydrofuran monosolvate

In the title cationic Cp(*)Fe(II) complex, [Fe(C(10)H(15))(CH(3)CN)(C(14)H(16)NP)]PF(6)·C(4)H(8)O, the metal ion is coordinated by the η (5)-Cp* ring as well as the P and N atoms of the chelating 2-(diphenyl­phosphino)ethyl­amine ligand and an additional acetonitrile mol­ecule in a piano-chair confo...

Descripción completa

Detalles Bibliográficos
Autores principales: Lee, Kajin, Rominger, Frank, Limbach, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212194/
https://www.ncbi.nlm.nih.gov/pubmed/22090896
http://dx.doi.org/10.1107/S1600536811028832
_version_ 1782215939786276864
author Lee, Kajin
Rominger, Frank
Limbach, Michael
author_facet Lee, Kajin
Rominger, Frank
Limbach, Michael
author_sort Lee, Kajin
collection PubMed
description In the title cationic Cp(*)Fe(II) complex, [Fe(C(10)H(15))(CH(3)CN)(C(14)H(16)NP)]PF(6)·C(4)H(8)O, the metal ion is coordinated by the η (5)-Cp* ring as well as the P and N atoms of the chelating 2-(diphenyl­phosphino)ethyl­amine ligand and an additional acetonitrile mol­ecule in a piano-chair conformation. The PF(6) (−) anion is disordered over two sets of sites with occupancies of 0.779 (7) and 0.221 (7).
format Online
Article
Text
id pubmed-3212194
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32121942011-11-16 (Acetonitrile-κN)[2-(diphenylphosphan­yl)ethanamine-κ(2) N,P][(1,2,3,4,5-η)-1,2,3,4,5-pentamethylcyclopentadienyl]iron(II) hexafluoridophosphate tetrahydrofuran monosolvate Lee, Kajin Rominger, Frank Limbach, Michael Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title cationic Cp(*)Fe(II) complex, [Fe(C(10)H(15))(CH(3)CN)(C(14)H(16)NP)]PF(6)·C(4)H(8)O, the metal ion is coordinated by the η (5)-Cp* ring as well as the P and N atoms of the chelating 2-(diphenyl­phosphino)ethyl­amine ligand and an additional acetonitrile mol­ecule in a piano-chair conformation. The PF(6) (−) anion is disordered over two sets of sites with occupancies of 0.779 (7) and 0.221 (7). International Union of Crystallography 2011-07-23 /pmc/articles/PMC3212194/ /pubmed/22090896 http://dx.doi.org/10.1107/S1600536811028832 Text en © Lee et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lee, Kajin
Rominger, Frank
Limbach, Michael
(Acetonitrile-κN)[2-(diphenylphosphan­yl)ethanamine-κ(2) N,P][(1,2,3,4,5-η)-1,2,3,4,5-pentamethylcyclopentadienyl]iron(II) hexafluoridophosphate tetrahydrofuran monosolvate
title (Acetonitrile-κN)[2-(diphenylphosphan­yl)ethanamine-κ(2) N,P][(1,2,3,4,5-η)-1,2,3,4,5-pentamethylcyclopentadienyl]iron(II) hexafluoridophosphate tetrahydrofuran monosolvate
title_full (Acetonitrile-κN)[2-(diphenylphosphan­yl)ethanamine-κ(2) N,P][(1,2,3,4,5-η)-1,2,3,4,5-pentamethylcyclopentadienyl]iron(II) hexafluoridophosphate tetrahydrofuran monosolvate
title_fullStr (Acetonitrile-κN)[2-(diphenylphosphan­yl)ethanamine-κ(2) N,P][(1,2,3,4,5-η)-1,2,3,4,5-pentamethylcyclopentadienyl]iron(II) hexafluoridophosphate tetrahydrofuran monosolvate
title_full_unstemmed (Acetonitrile-κN)[2-(diphenylphosphan­yl)ethanamine-κ(2) N,P][(1,2,3,4,5-η)-1,2,3,4,5-pentamethylcyclopentadienyl]iron(II) hexafluoridophosphate tetrahydrofuran monosolvate
title_short (Acetonitrile-κN)[2-(diphenylphosphan­yl)ethanamine-κ(2) N,P][(1,2,3,4,5-η)-1,2,3,4,5-pentamethylcyclopentadienyl]iron(II) hexafluoridophosphate tetrahydrofuran monosolvate
title_sort (acetonitrile-κn)[2-(diphenylphosphan­yl)ethanamine-κ(2) n,p][(1,2,3,4,5-η)-1,2,3,4,5-pentamethylcyclopentadienyl]iron(ii) hexafluoridophosphate tetrahydrofuran monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212194/
https://www.ncbi.nlm.nih.gov/pubmed/22090896
http://dx.doi.org/10.1107/S1600536811028832
work_keys_str_mv AT leekajin acetonitrilekn2diphenylphosphanylethanaminek2np12345ē12345pentamethylcyclopentadienylironiihexafluoridophosphatetetrahydrofuranmonosolvate
AT romingerfrank acetonitrilekn2diphenylphosphanylethanaminek2np12345ē12345pentamethylcyclopentadienylironiihexafluoridophosphatetetrahydrofuranmonosolvate
AT limbachmichael acetonitrilekn2diphenylphosphanylethanaminek2np12345ē12345pentamethylcyclopentadienylironiihexafluoridophosphatetetrahydrofuranmonosolvate

Ejemplares similares