catena-Poly[[(nitrito-κ(2) O,O′)silver(I)]-μ-1,2-bis­[1-(pyridin-4-yl)ethyl­idene]hydrazine-κ(2) N:N′]

The asymmetric unit of the title compound, [Ag(NO(2))(C(14)H(14)N(4))](n), contains half of the repeating formula unit (Z′ = 1/2). The Ag(I) ion lies on a twofold rotation axis. The primary structure consists of a one-dimensional coordination polymer formed by the Ag(I) ions and the bipyridyl azine...

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Detalles Bibliográficos
Autores principales: Kennedy, Alan R., Okoth, Maurice O., Walsh, David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212196/
https://www.ncbi.nlm.nih.gov/pubmed/22090898
http://dx.doi.org/10.1107/S1600536811028546
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author Kennedy, Alan R.
Okoth, Maurice O.
Walsh, David
author_facet Kennedy, Alan R.
Okoth, Maurice O.
Walsh, David
author_sort Kennedy, Alan R.
collection PubMed
description The asymmetric unit of the title compound, [Ag(NO(2))(C(14)H(14)N(4))](n), contains half of the repeating formula unit (Z′ = 1/2). The Ag(I) ion lies on a twofold rotation axis. The primary structure consists of a one-dimensional coordination polymer formed by the Ag(I) ions and the bipyridyl azine ligand in which there is an inversion center at the mid-point of the N—N bond. The nitrite anion inter­acts with the Ag(I) ion through a chelating μ(2) inter­action involving both O atoms. In the crystal, the coordination chains are parallel and inter­act through Ag⋯π [3.220 (2) Å] and π–π [3.489 (3) Å] inter­actions.
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spelling pubmed-32121962011-11-16 catena-Poly[[(nitrito-κ(2) O,O′)silver(I)]-μ-1,2-bis­[1-(pyridin-4-yl)ethyl­idene]hydrazine-κ(2) N:N′] Kennedy, Alan R. Okoth, Maurice O. Walsh, David Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Ag(NO(2))(C(14)H(14)N(4))](n), contains half of the repeating formula unit (Z′ = 1/2). The Ag(I) ion lies on a twofold rotation axis. The primary structure consists of a one-dimensional coordination polymer formed by the Ag(I) ions and the bipyridyl azine ligand in which there is an inversion center at the mid-point of the N—N bond. The nitrite anion inter­acts with the Ag(I) ion through a chelating μ(2) inter­action involving both O atoms. In the crystal, the coordination chains are parallel and inter­act through Ag⋯π [3.220 (2) Å] and π–π [3.489 (3) Å] inter­actions. International Union of Crystallography 2011-07-23 /pmc/articles/PMC3212196/ /pubmed/22090898 http://dx.doi.org/10.1107/S1600536811028546 Text en © Kennedy et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kennedy, Alan R.
Okoth, Maurice O.
Walsh, David
catena-Poly[[(nitrito-κ(2) O,O′)silver(I)]-μ-1,2-bis­[1-(pyridin-4-yl)ethyl­idene]hydrazine-κ(2) N:N′]
title catena-Poly[[(nitrito-κ(2) O,O′)silver(I)]-μ-1,2-bis­[1-(pyridin-4-yl)ethyl­idene]hydrazine-κ(2) N:N′]
title_full catena-Poly[[(nitrito-κ(2) O,O′)silver(I)]-μ-1,2-bis­[1-(pyridin-4-yl)ethyl­idene]hydrazine-κ(2) N:N′]
title_fullStr catena-Poly[[(nitrito-κ(2) O,O′)silver(I)]-μ-1,2-bis­[1-(pyridin-4-yl)ethyl­idene]hydrazine-κ(2) N:N′]
title_full_unstemmed catena-Poly[[(nitrito-κ(2) O,O′)silver(I)]-μ-1,2-bis­[1-(pyridin-4-yl)ethyl­idene]hydrazine-κ(2) N:N′]
title_short catena-Poly[[(nitrito-κ(2) O,O′)silver(I)]-μ-1,2-bis­[1-(pyridin-4-yl)ethyl­idene]hydrazine-κ(2) N:N′]
title_sort catena-poly[[(nitrito-κ(2) o,o′)silver(i)]-μ-1,2-bis­[1-(pyridin-4-yl)ethyl­idene]hydrazine-κ(2) n:n′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212196/
https://www.ncbi.nlm.nih.gov/pubmed/22090898
http://dx.doi.org/10.1107/S1600536811028546
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