trans-Bis(acetato-κO)diaquabis­(2-amino­pyrazine-κN (4))manganese(II) dihydrate

The Mn(II) atom in the title compound, [Mn(CH(3)COO)(2)(C(4)H(5)N(3))(2)(H(2)O)(2)]·2H(2)O, is situated on a center of inversion and shows an octa­hedral coordination polyhedron made up by four O atoms and two N atoms. The octa­hedron is somewhat tetra­gonally distorted owing to the longer Mn—N bond...

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Detalles Bibliográficos
Autores principales: Gao, Shan, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212198/
https://www.ncbi.nlm.nih.gov/pubmed/22090900
http://dx.doi.org/10.1107/S1600536811028583
Descripción
Sumario:The Mn(II) atom in the title compound, [Mn(CH(3)COO)(2)(C(4)H(5)N(3))(2)(H(2)O)(2)]·2H(2)O, is situated on a center of inversion and shows an octa­hedral coordination polyhedron made up by four O atoms and two N atoms. The octa­hedron is somewhat tetra­gonally distorted owing to the longer Mn—N bond [2.323 (3) Å]. The mononuclear complex mol­ecule and uncoordinated water mol­ecules are linked by O—H⋯N, N—H⋯O and O—H⋯O hydrogen bonds, generating a three-dimensional network.

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