trans-Bis(acetato-κO)diaquabis­(2-amino­pyrazine-κN (4))manganese(II) dihydrate

The Mn(II) atom in the title compound, [Mn(CH(3)COO)(2)(C(4)H(5)N(3))(2)(H(2)O)(2)]·2H(2)O, is situated on a center of inversion and shows an octa­hedral coordination polyhedron made up by four O atoms and two N atoms. The octa­hedron is somewhat tetra­gonally distorted owing to the longer Mn—N bond...

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Detalles Bibliográficos
Autores principales: Gao, Shan, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212198/
https://www.ncbi.nlm.nih.gov/pubmed/22090900
http://dx.doi.org/10.1107/S1600536811028583
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author Gao, Shan
Ng, Seik Weng
author_facet Gao, Shan
Ng, Seik Weng
author_sort Gao, Shan
collection PubMed
description The Mn(II) atom in the title compound, [Mn(CH(3)COO)(2)(C(4)H(5)N(3))(2)(H(2)O)(2)]·2H(2)O, is situated on a center of inversion and shows an octa­hedral coordination polyhedron made up by four O atoms and two N atoms. The octa­hedron is somewhat tetra­gonally distorted owing to the longer Mn—N bond [2.323 (3) Å]. The mononuclear complex mol­ecule and uncoordinated water mol­ecules are linked by O—H⋯N, N—H⋯O and O—H⋯O hydrogen bonds, generating a three-dimensional network.
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spelling pubmed-32121982011-11-16 trans-Bis(acetato-κO)diaquabis­(2-amino­pyrazine-κN (4))manganese(II) dihydrate Gao, Shan Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Mn(II) atom in the title compound, [Mn(CH(3)COO)(2)(C(4)H(5)N(3))(2)(H(2)O)(2)]·2H(2)O, is situated on a center of inversion and shows an octa­hedral coordination polyhedron made up by four O atoms and two N atoms. The octa­hedron is somewhat tetra­gonally distorted owing to the longer Mn—N bond [2.323 (3) Å]. The mononuclear complex mol­ecule and uncoordinated water mol­ecules are linked by O—H⋯N, N—H⋯O and O—H⋯O hydrogen bonds, generating a three-dimensional network. International Union of Crystallography 2011-07-23 /pmc/articles/PMC3212198/ /pubmed/22090900 http://dx.doi.org/10.1107/S1600536811028583 Text en © Gao and Ng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Shan
Ng, Seik Weng
trans-Bis(acetato-κO)diaquabis­(2-amino­pyrazine-κN (4))manganese(II) dihydrate
title trans-Bis(acetato-κO)diaquabis­(2-amino­pyrazine-κN (4))manganese(II) dihydrate
title_full trans-Bis(acetato-κO)diaquabis­(2-amino­pyrazine-κN (4))manganese(II) dihydrate
title_fullStr trans-Bis(acetato-κO)diaquabis­(2-amino­pyrazine-κN (4))manganese(II) dihydrate
title_full_unstemmed trans-Bis(acetato-κO)diaquabis­(2-amino­pyrazine-κN (4))manganese(II) dihydrate
title_short trans-Bis(acetato-κO)diaquabis­(2-amino­pyrazine-κN (4))manganese(II) dihydrate
title_sort trans-bis(acetato-κo)diaquabis­(2-amino­pyrazine-κn (4))manganese(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212198/
https://www.ncbi.nlm.nih.gov/pubmed/22090900
http://dx.doi.org/10.1107/S1600536811028583
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