Bis[1-(4-chloro­benz­yl)pyridinium] bis­(1,2,5-thia­diazole-3,4-dithiol­ato)nickelate(II)

The asymmetric unit of the salt, (C(12)H(11)ClN)(2)[Ni(C(2)N(2)S(3))(2)], comprises one cation and a half of Ni(tdas)(2) (tdas = 1,2,5-thia­diazole-3,4-dithiol­ate) anion. The Ni(II) atom is located at a centre of inversion. The Ni(II) atom has a square-planar coordination with Ni—S distances of 2.2...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Zhi-min, Wang, Fang-quan, Liu, Zi-yang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212200/
https://www.ncbi.nlm.nih.gov/pubmed/22090902
http://dx.doi.org/10.1107/S160053681102873X
Descripción
Sumario:The asymmetric unit of the salt, (C(12)H(11)ClN)(2)[Ni(C(2)N(2)S(3))(2)], comprises one cation and a half of Ni(tdas)(2) (tdas = 1,2,5-thia­diazole-3,4-dithiol­ate) anion. The Ni(II) atom is located at a centre of inversion. The Ni(II) atom has a square-planar coordination with Ni—S distances of 2.2052 (4) and 2.1970 (5) Å. In crystal, weak C—H⋯S and C—H⋯Ni contacts are observed between the anions and cations.

Ejemplares similares