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{2,2′-[(2,2-Dimethylpropane-1,3-diyldinitrilo)bis(phenylmethylidyne)]diphenolato}copper(II)
The complete molecule of the title complex, [Cu(C(31)H(28)N(2)O(2))], is generated by the application of twofold symmetry; the Cu and CMe(2) atoms lie on the axis. The geometry around the Cu(II) atom is distorted square-planar. The dihedral angle between the two phenyl rings is 76.0 (3) °. The crys...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212202/ https://www.ncbi.nlm.nih.gov/pubmed/22090904 http://dx.doi.org/10.1107/S1600536811028844 |
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author | Kargar, Hadi Kia, Reza Moghadam, Majid Froozandeh, Fatemeh Tahir, Muhammad Nawaz |
author_facet | Kargar, Hadi Kia, Reza Moghadam, Majid Froozandeh, Fatemeh Tahir, Muhammad Nawaz |
author_sort | Kargar, Hadi |
collection | PubMed |
description | The complete molecule of the title complex, [Cu(C(31)H(28)N(2)O(2))], is generated by the application of twofold symmetry; the Cu and CMe(2) atoms lie on the axis. The geometry around the Cu(II) atom is distorted square-planar. The dihedral angle between the two phenyl rings is 76.0 (3) °. The crystal packing is stabilized by intermolecular C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-3212202 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32122022011-11-16 {2,2′-[(2,2-Dimethylpropane-1,3-diyldinitrilo)bis(phenylmethylidyne)]diphenolato}copper(II) Kargar, Hadi Kia, Reza Moghadam, Majid Froozandeh, Fatemeh Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complete molecule of the title complex, [Cu(C(31)H(28)N(2)O(2))], is generated by the application of twofold symmetry; the Cu and CMe(2) atoms lie on the axis. The geometry around the Cu(II) atom is distorted square-planar. The dihedral angle between the two phenyl rings is 76.0 (3) °. The crystal packing is stabilized by intermolecular C—H⋯π interactions. International Union of Crystallography 2011-07-23 /pmc/articles/PMC3212202/ /pubmed/22090904 http://dx.doi.org/10.1107/S1600536811028844 Text en © Kargar et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kargar, Hadi Kia, Reza Moghadam, Majid Froozandeh, Fatemeh Tahir, Muhammad Nawaz {2,2′-[(2,2-Dimethylpropane-1,3-diyldinitrilo)bis(phenylmethylidyne)]diphenolato}copper(II) |
title | {2,2′-[(2,2-Dimethylpropane-1,3-diyldinitrilo)bis(phenylmethylidyne)]diphenolato}copper(II) |
title_full | {2,2′-[(2,2-Dimethylpropane-1,3-diyldinitrilo)bis(phenylmethylidyne)]diphenolato}copper(II) |
title_fullStr | {2,2′-[(2,2-Dimethylpropane-1,3-diyldinitrilo)bis(phenylmethylidyne)]diphenolato}copper(II) |
title_full_unstemmed | {2,2′-[(2,2-Dimethylpropane-1,3-diyldinitrilo)bis(phenylmethylidyne)]diphenolato}copper(II) |
title_short | {2,2′-[(2,2-Dimethylpropane-1,3-diyldinitrilo)bis(phenylmethylidyne)]diphenolato}copper(II) |
title_sort | {2,2′-[(2,2-dimethylpropane-1,3-diyldinitrilo)bis(phenylmethylidyne)]diphenolato}copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212202/ https://www.ncbi.nlm.nih.gov/pubmed/22090904 http://dx.doi.org/10.1107/S1600536811028844 |
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