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{μ-N,N,N′,N′-Tetrakis[(diphenylphosphanyl)methyl]benzene-1,4-diamine}bis[(2,2′-bipyridyl)copper(I)] bis(tetrafluoridoborate)
In the title compound, [Cu(2)(C(10)H(8)N(2))(2)(C(58)H(52)N(2)P(4))](BF(4))(2), the dinuclear cation lies on an inversion centre. The Cu(I) atom is coordinated by two N atoms from a 2,2′-bipyridine ligand and two P atoms from an N,N,N′,N′-tetrakis[(diphenylphosphanyl)methyl]benzene-1,4-diamine...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212203/ https://www.ncbi.nlm.nih.gov/pubmed/22090905 http://dx.doi.org/10.1107/S1600536811029333 |
Sumario: | In the title compound, [Cu(2)(C(10)H(8)N(2))(2)(C(58)H(52)N(2)P(4))](BF(4))(2), the dinuclear cation lies on an inversion centre. The Cu(I) atom is coordinated by two N atoms from a 2,2′-bipyridine ligand and two P atoms from an N,N,N′,N′-tetrakis[(diphenylphosphanyl)methyl]benzene-1,4-diamine ligand in a distorted tetrahedral geometry. In the crystal, intermolecular C—H⋯F hydrogen bonds link the ions into layers parallel to [[Image: see text]01]. π–π interactions [centroid–centroid distance = 3.668 (4) Å] are also observed. One F atom of the anion is disordered over two orientations with a refined occupancy ratio of 0.675 (13):0.325 (13). |
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