μ-Oxido-bis­[bis­(penta­fluoro­phenolato)(η(5)-penta­methyl­cyclo­penta­dien­yl)titanium(IV)]

The dinuclear title complex, [Ti(2)(C(10)H(15))(2)(C(6)F(5)O)(4)O], features two Ti(IV) atoms bridged by an O atom, which lies on an inversion centre. The Ti(IV) atom is bonded to a η(5)-penta­methyl­cyclo­penta­dienyl ring, two penta­fluoro­phenolate anions and to the bridging O atom. The environme...

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Detalles Bibliográficos
Autores principales: Lee, Junseong, Kim, Youngjo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212204/
https://www.ncbi.nlm.nih.gov/pubmed/22090906
http://dx.doi.org/10.1107/S1600536811029357
Descripción
Sumario:The dinuclear title complex, [Ti(2)(C(10)H(15))(2)(C(6)F(5)O)(4)O], features two Ti(IV) atoms bridged by an O atom, which lies on an inversion centre. The Ti(IV) atom is bonded to a η(5)-penta­methyl­cyclo­penta­dienyl ring, two penta­fluoro­phenolate anions and to the bridging O atom. The environment around the Ti(IV) atom can be considered as a distorted tetra­hedron. The cyclo­penta­dienyl ring is disordered over two sets of sites [site occupancy = 0.824 (8) for the major component].

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