μ-Oxido-bis­[bis­(penta­fluoro­phenolato)(η(5)-penta­methyl­cyclo­penta­dien­yl)titanium(IV)]

The dinuclear title complex, [Ti(2)(C(10)H(15))(2)(C(6)F(5)O)(4)O], features two Ti(IV) atoms bridged by an O atom, which lies on an inversion centre. The Ti(IV) atom is bonded to a η(5)-penta­methyl­cyclo­penta­dienyl ring, two penta­fluoro­phenolate anions and to the bridging O atom. The environme...

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Detalles Bibliográficos
Autores principales: Lee, Junseong, Kim, Youngjo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212204/
https://www.ncbi.nlm.nih.gov/pubmed/22090906
http://dx.doi.org/10.1107/S1600536811029357
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author Lee, Junseong
Kim, Youngjo
author_facet Lee, Junseong
Kim, Youngjo
author_sort Lee, Junseong
collection PubMed
description The dinuclear title complex, [Ti(2)(C(10)H(15))(2)(C(6)F(5)O)(4)O], features two Ti(IV) atoms bridged by an O atom, which lies on an inversion centre. The Ti(IV) atom is bonded to a η(5)-penta­methyl­cyclo­penta­dienyl ring, two penta­fluoro­phenolate anions and to the bridging O atom. The environment around the Ti(IV) atom can be considered as a distorted tetra­hedron. The cyclo­penta­dienyl ring is disordered over two sets of sites [site occupancy = 0.824 (8) for the major component].
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spelling pubmed-32122042011-11-16 μ-Oxido-bis­[bis­(penta­fluoro­phenolato)(η(5)-penta­methyl­cyclo­penta­dien­yl)titanium(IV)] Lee, Junseong Kim, Youngjo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The dinuclear title complex, [Ti(2)(C(10)H(15))(2)(C(6)F(5)O)(4)O], features two Ti(IV) atoms bridged by an O atom, which lies on an inversion centre. The Ti(IV) atom is bonded to a η(5)-penta­methyl­cyclo­penta­dienyl ring, two penta­fluoro­phenolate anions and to the bridging O atom. The environment around the Ti(IV) atom can be considered as a distorted tetra­hedron. The cyclo­penta­dienyl ring is disordered over two sets of sites [site occupancy = 0.824 (8) for the major component]. International Union of Crystallography 2011-07-30 /pmc/articles/PMC3212204/ /pubmed/22090906 http://dx.doi.org/10.1107/S1600536811029357 Text en © Lee and Kim 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lee, Junseong
Kim, Youngjo
μ-Oxido-bis­[bis­(penta­fluoro­phenolato)(η(5)-penta­methyl­cyclo­penta­dien­yl)titanium(IV)]
title μ-Oxido-bis­[bis­(penta­fluoro­phenolato)(η(5)-penta­methyl­cyclo­penta­dien­yl)titanium(IV)]
title_full μ-Oxido-bis­[bis­(penta­fluoro­phenolato)(η(5)-penta­methyl­cyclo­penta­dien­yl)titanium(IV)]
title_fullStr μ-Oxido-bis­[bis­(penta­fluoro­phenolato)(η(5)-penta­methyl­cyclo­penta­dien­yl)titanium(IV)]
title_full_unstemmed μ-Oxido-bis­[bis­(penta­fluoro­phenolato)(η(5)-penta­methyl­cyclo­penta­dien­yl)titanium(IV)]
title_short μ-Oxido-bis­[bis­(penta­fluoro­phenolato)(η(5)-penta­methyl­cyclo­penta­dien­yl)titanium(IV)]
title_sort μ-oxido-bis­[bis­(penta­fluoro­phenolato)(η(5)-penta­methyl­cyclo­penta­dien­yl)titanium(iv)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212204/
https://www.ncbi.nlm.nih.gov/pubmed/22090906
http://dx.doi.org/10.1107/S1600536811029357
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