Cargando…

Combined plasma gas-phase synthesis and colloidal processing of InP/ZnS core/shell nanocrystals

Indium phosphide nanocrystals (InP NCs) with diameters ranging from 2 to 5 nm were synthesized with a scalable, flow-through, nonthermal plasma process at a rate ranging from 10 to 40 mg/h. The NC size is controlled through the plasma operating parameters, with the residence time of the gas in the p...

Descripción completa

Detalles Bibliográficos
Autores principales: Gresback, Ryan, Hue, Ryan, Gladfelter, Wayne L, Kortshagen, Uwe R
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212215/
https://www.ncbi.nlm.nih.gov/pubmed/21711589
http://dx.doi.org/10.1186/1556-276X-6-68
_version_ 1782215944604483584
author Gresback, Ryan
Hue, Ryan
Gladfelter, Wayne L
Kortshagen, Uwe R
author_facet Gresback, Ryan
Hue, Ryan
Gladfelter, Wayne L
Kortshagen, Uwe R
author_sort Gresback, Ryan
collection PubMed
description Indium phosphide nanocrystals (InP NCs) with diameters ranging from 2 to 5 nm were synthesized with a scalable, flow-through, nonthermal plasma process at a rate ranging from 10 to 40 mg/h. The NC size is controlled through the plasma operating parameters, with the residence time of the gas in the plasma region strongly influencing the NC size. The NC size distribution is narrow with the standard deviation being less than 20% of the mean NC size. Zinc sulfide (ZnS) shells were grown around the plasma-synthesized InP NCs in a liquid phase reaction. Photoluminescence with quantum yields as high as 15% were observed for the InP/ZnS core-shell NCs.
format Online
Article
Text
id pubmed-3212215
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher Springer
record_format MEDLINE/PubMed
spelling pubmed-32122152011-11-09 Combined plasma gas-phase synthesis and colloidal processing of InP/ZnS core/shell nanocrystals Gresback, Ryan Hue, Ryan Gladfelter, Wayne L Kortshagen, Uwe R Nanoscale Res Lett Nano Express Indium phosphide nanocrystals (InP NCs) with diameters ranging from 2 to 5 nm were synthesized with a scalable, flow-through, nonthermal plasma process at a rate ranging from 10 to 40 mg/h. The NC size is controlled through the plasma operating parameters, with the residence time of the gas in the plasma region strongly influencing the NC size. The NC size distribution is narrow with the standard deviation being less than 20% of the mean NC size. Zinc sulfide (ZnS) shells were grown around the plasma-synthesized InP NCs in a liquid phase reaction. Photoluminescence with quantum yields as high as 15% were observed for the InP/ZnS core-shell NCs. Springer 2011-01-12 /pmc/articles/PMC3212215/ /pubmed/21711589 http://dx.doi.org/10.1186/1556-276X-6-68 Text en Copyright ©2011 Gresback et al; licensee Springer. http://creativecommons.org/licenses/by/2.0 This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Nano Express
Gresback, Ryan
Hue, Ryan
Gladfelter, Wayne L
Kortshagen, Uwe R
Combined plasma gas-phase synthesis and colloidal processing of InP/ZnS core/shell nanocrystals
title Combined plasma gas-phase synthesis and colloidal processing of InP/ZnS core/shell nanocrystals
title_full Combined plasma gas-phase synthesis and colloidal processing of InP/ZnS core/shell nanocrystals
title_fullStr Combined plasma gas-phase synthesis and colloidal processing of InP/ZnS core/shell nanocrystals
title_full_unstemmed Combined plasma gas-phase synthesis and colloidal processing of InP/ZnS core/shell nanocrystals
title_short Combined plasma gas-phase synthesis and colloidal processing of InP/ZnS core/shell nanocrystals
title_sort combined plasma gas-phase synthesis and colloidal processing of inp/zns core/shell nanocrystals
topic Nano Express
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212215/
https://www.ncbi.nlm.nih.gov/pubmed/21711589
http://dx.doi.org/10.1186/1556-276X-6-68
work_keys_str_mv AT gresbackryan combinedplasmagasphasesynthesisandcolloidalprocessingofinpznscoreshellnanocrystals
AT hueryan combinedplasmagasphasesynthesisandcolloidalprocessingofinpznscoreshellnanocrystals
AT gladfelterwaynel combinedplasmagasphasesynthesisandcolloidalprocessingofinpznscoreshellnanocrystals
AT kortshagenuwer combinedplasmagasphasesynthesisandcolloidalprocessingofinpznscoreshellnanocrystals