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Tetrakis(acetonitrile-κN)lithium hexafluoridophosphate acetonitrile monosolvate
In the title compound, [Li(CH(3)CN)(4)]PF(6)·CH(3)CN, the asymmetric unit consists of three independent tetrahedral [Li(CH(3)CN)(4)](+) cations, three uncoordinated PF(6) (−) anions and three uncoordinated CH(3)CN solvent molecules. The three anions are disordered over two sites through a rotation...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212250/ https://www.ncbi.nlm.nih.gov/pubmed/22090907 http://dx.doi.org/10.1107/S1600536811027528 |
| _version_ | 1782215952533815296 |
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| author | Seo, Daniel M. Boyle, Paul D. Henderson, Wesley A. |
| author_facet | Seo, Daniel M. Boyle, Paul D. Henderson, Wesley A. |
| author_sort | Seo, Daniel M. |
| collection | PubMed |
| description | In the title compound, [Li(CH(3)CN)(4)]PF(6)·CH(3)CN, the asymmetric unit consists of three independent tetrahedral [Li(CH(3)CN)(4)](+) cations, three uncoordinated PF(6) (−) anions and three uncoordinated CH(3)CN solvent molecules. The three anions are disordered over two sites through a rotation along one of the F—P—F axes. The relative occupancies of the two sites for the F atoms are 0.643 (16):0.357 (16), 0.677 (10):0.323 (10) and 0.723 (13):0.277 (13). The crystal used was a racemic twin, with approximately equal twin components. |
| format | Online Article Text |
| id | pubmed-3212250 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32122502011-11-16 Tetrakis(acetonitrile-κN)lithium hexafluoridophosphate acetonitrile monosolvate Seo, Daniel M. Boyle, Paul D. Henderson, Wesley A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Li(CH(3)CN)(4)]PF(6)·CH(3)CN, the asymmetric unit consists of three independent tetrahedral [Li(CH(3)CN)(4)](+) cations, three uncoordinated PF(6) (−) anions and three uncoordinated CH(3)CN solvent molecules. The three anions are disordered over two sites through a rotation along one of the F—P—F axes. The relative occupancies of the two sites for the F atoms are 0.643 (16):0.357 (16), 0.677 (10):0.323 (10) and 0.723 (13):0.277 (13). The crystal used was a racemic twin, with approximately equal twin components. International Union of Crystallography 2011-07-30 /pmc/articles/PMC3212250/ /pubmed/22090907 http://dx.doi.org/10.1107/S1600536811027528 Text en © Seo et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Seo, Daniel M. Boyle, Paul D. Henderson, Wesley A. Tetrakis(acetonitrile-κN)lithium hexafluoridophosphate acetonitrile monosolvate |
| title | Tetrakis(acetonitrile-κN)lithium hexafluoridophosphate acetonitrile monosolvate |
| title_full | Tetrakis(acetonitrile-κN)lithium hexafluoridophosphate acetonitrile monosolvate |
| title_fullStr | Tetrakis(acetonitrile-κN)lithium hexafluoridophosphate acetonitrile monosolvate |
| title_full_unstemmed | Tetrakis(acetonitrile-κN)lithium hexafluoridophosphate acetonitrile monosolvate |
| title_short | Tetrakis(acetonitrile-κN)lithium hexafluoridophosphate acetonitrile monosolvate |
| title_sort | tetrakis(acetonitrile-κn)lithium hexafluoridophosphate acetonitrile monosolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212250/ https://www.ncbi.nlm.nih.gov/pubmed/22090907 http://dx.doi.org/10.1107/S1600536811027528 |
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