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Bis(μ-4-amino-3,5-dimethyl-4H-1,2,4-triazole-κ (2) N (1):N (2))bis­(dibromidozinc)

The centrosymmetric dimeric title complex, [Zn(2)Br(4)(C(4)H(8)N(4))(2)], is isotypic with its [Zn(2)Cl(4)(C(4)H(8)N(4))(2)], [Zn(2)I(4)(C(4)H(8)N(4))(2)] and [Co(2)Cl(4)(C(4)H(8)N(4))(2)] analogues. The zinc atom is bonded to two N atoms belonging to triazole bridging rings and to two terminal brom...

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Detalles Bibliográficos
Autores principales: Zhu, Xia, Guo, Ying, Li, Jian-Gang, Wu, Yao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212254/
https://www.ncbi.nlm.nih.gov/pubmed/22090911
http://dx.doi.org/10.1107/S1600536811028789
Descripción
Sumario:The centrosymmetric dimeric title complex, [Zn(2)Br(4)(C(4)H(8)N(4))(2)], is isotypic with its [Zn(2)Cl(4)(C(4)H(8)N(4))(2)], [Zn(2)I(4)(C(4)H(8)N(4))(2)] and [Co(2)Cl(4)(C(4)H(8)N(4))(2)] analogues. The zinc atom is bonded to two N atoms belonging to triazole bridging rings and to two terminal bromide ligands, in a geometry close to tetra­hedral. Weak N—H⋯Br hydrogen bonds, with the amine functions as donor groups, are observed in the crystal structure, forming a three-dimensional supra­molecular network.