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Bis(μ-4-amino-3,5-dimethyl-4H-1,2,4-triazole-κ (2) N (1):N (2))bis­(dibromidozinc)

The centrosymmetric dimeric title complex, [Zn(2)Br(4)(C(4)H(8)N(4))(2)], is isotypic with its [Zn(2)Cl(4)(C(4)H(8)N(4))(2)], [Zn(2)I(4)(C(4)H(8)N(4))(2)] and [Co(2)Cl(4)(C(4)H(8)N(4))(2)] analogues. The zinc atom is bonded to two N atoms belonging to triazole bridging rings and to two terminal brom...

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Detalles Bibliográficos
Autores principales: Zhu, Xia, Guo, Ying, Li, Jian-Gang, Wu, Yao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212254/
https://www.ncbi.nlm.nih.gov/pubmed/22090911
http://dx.doi.org/10.1107/S1600536811028789
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author Zhu, Xia
Guo, Ying
Li, Jian-Gang
Wu, Yao
author_facet Zhu, Xia
Guo, Ying
Li, Jian-Gang
Wu, Yao
author_sort Zhu, Xia
collection PubMed
description The centrosymmetric dimeric title complex, [Zn(2)Br(4)(C(4)H(8)N(4))(2)], is isotypic with its [Zn(2)Cl(4)(C(4)H(8)N(4))(2)], [Zn(2)I(4)(C(4)H(8)N(4))(2)] and [Co(2)Cl(4)(C(4)H(8)N(4))(2)] analogues. The zinc atom is bonded to two N atoms belonging to triazole bridging rings and to two terminal bromide ligands, in a geometry close to tetra­hedral. Weak N—H⋯Br hydrogen bonds, with the amine functions as donor groups, are observed in the crystal structure, forming a three-dimensional supra­molecular network.
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spelling pubmed-32122542011-11-16 Bis(μ-4-amino-3,5-dimethyl-4H-1,2,4-triazole-κ (2) N (1):N (2))bis­(dibromidozinc) Zhu, Xia Guo, Ying Li, Jian-Gang Wu, Yao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The centrosymmetric dimeric title complex, [Zn(2)Br(4)(C(4)H(8)N(4))(2)], is isotypic with its [Zn(2)Cl(4)(C(4)H(8)N(4))(2)], [Zn(2)I(4)(C(4)H(8)N(4))(2)] and [Co(2)Cl(4)(C(4)H(8)N(4))(2)] analogues. The zinc atom is bonded to two N atoms belonging to triazole bridging rings and to two terminal bromide ligands, in a geometry close to tetra­hedral. Weak N—H⋯Br hydrogen bonds, with the amine functions as donor groups, are observed in the crystal structure, forming a three-dimensional supra­molecular network. International Union of Crystallography 2011-07-30 /pmc/articles/PMC3212254/ /pubmed/22090911 http://dx.doi.org/10.1107/S1600536811028789 Text en © Zhu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Xia
Guo, Ying
Li, Jian-Gang
Wu, Yao
Bis(μ-4-amino-3,5-dimethyl-4H-1,2,4-triazole-κ (2) N (1):N (2))bis­(dibromidozinc)
title Bis(μ-4-amino-3,5-dimethyl-4H-1,2,4-triazole-κ (2) N (1):N (2))bis­(dibromidozinc)
title_full Bis(μ-4-amino-3,5-dimethyl-4H-1,2,4-triazole-κ (2) N (1):N (2))bis­(dibromidozinc)
title_fullStr Bis(μ-4-amino-3,5-dimethyl-4H-1,2,4-triazole-κ (2) N (1):N (2))bis­(dibromidozinc)
title_full_unstemmed Bis(μ-4-amino-3,5-dimethyl-4H-1,2,4-triazole-κ (2) N (1):N (2))bis­(dibromidozinc)
title_short Bis(μ-4-amino-3,5-dimethyl-4H-1,2,4-triazole-κ (2) N (1):N (2))bis­(dibromidozinc)
title_sort bis(μ-4-amino-3,5-dimethyl-4h-1,2,4-triazole-κ (2) n (1):n (2))bis­(dibromidozinc)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212254/
https://www.ncbi.nlm.nih.gov/pubmed/22090911
http://dx.doi.org/10.1107/S1600536811028789
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