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Bis(μ-4-amino-3,5-dimethyl-4H-1,2,4-triazole-κ (2) N (1):N (2))bis(dibromidozinc)
The centrosymmetric dimeric title complex, [Zn(2)Br(4)(C(4)H(8)N(4))(2)], is isotypic with its [Zn(2)Cl(4)(C(4)H(8)N(4))(2)], [Zn(2)I(4)(C(4)H(8)N(4))(2)] and [Co(2)Cl(4)(C(4)H(8)N(4))(2)] analogues. The zinc atom is bonded to two N atoms belonging to triazole bridging rings and to two terminal brom...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212254/ https://www.ncbi.nlm.nih.gov/pubmed/22090911 http://dx.doi.org/10.1107/S1600536811028789 |
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author | Zhu, Xia Guo, Ying Li, Jian-Gang Wu, Yao |
author_facet | Zhu, Xia Guo, Ying Li, Jian-Gang Wu, Yao |
author_sort | Zhu, Xia |
collection | PubMed |
description | The centrosymmetric dimeric title complex, [Zn(2)Br(4)(C(4)H(8)N(4))(2)], is isotypic with its [Zn(2)Cl(4)(C(4)H(8)N(4))(2)], [Zn(2)I(4)(C(4)H(8)N(4))(2)] and [Co(2)Cl(4)(C(4)H(8)N(4))(2)] analogues. The zinc atom is bonded to two N atoms belonging to triazole bridging rings and to two terminal bromide ligands, in a geometry close to tetrahedral. Weak N—H⋯Br hydrogen bonds, with the amine functions as donor groups, are observed in the crystal structure, forming a three-dimensional supramolecular network. |
format | Online Article Text |
id | pubmed-3212254 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32122542011-11-16 Bis(μ-4-amino-3,5-dimethyl-4H-1,2,4-triazole-κ (2) N (1):N (2))bis(dibromidozinc) Zhu, Xia Guo, Ying Li, Jian-Gang Wu, Yao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The centrosymmetric dimeric title complex, [Zn(2)Br(4)(C(4)H(8)N(4))(2)], is isotypic with its [Zn(2)Cl(4)(C(4)H(8)N(4))(2)], [Zn(2)I(4)(C(4)H(8)N(4))(2)] and [Co(2)Cl(4)(C(4)H(8)N(4))(2)] analogues. The zinc atom is bonded to two N atoms belonging to triazole bridging rings and to two terminal bromide ligands, in a geometry close to tetrahedral. Weak N—H⋯Br hydrogen bonds, with the amine functions as donor groups, are observed in the crystal structure, forming a three-dimensional supramolecular network. International Union of Crystallography 2011-07-30 /pmc/articles/PMC3212254/ /pubmed/22090911 http://dx.doi.org/10.1107/S1600536811028789 Text en © Zhu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhu, Xia Guo, Ying Li, Jian-Gang Wu, Yao Bis(μ-4-amino-3,5-dimethyl-4H-1,2,4-triazole-κ (2) N (1):N (2))bis(dibromidozinc) |
title | Bis(μ-4-amino-3,5-dimethyl-4H-1,2,4-triazole-κ
(2)
N
(1):N
(2))bis(dibromidozinc) |
title_full | Bis(μ-4-amino-3,5-dimethyl-4H-1,2,4-triazole-κ
(2)
N
(1):N
(2))bis(dibromidozinc) |
title_fullStr | Bis(μ-4-amino-3,5-dimethyl-4H-1,2,4-triazole-κ
(2)
N
(1):N
(2))bis(dibromidozinc) |
title_full_unstemmed | Bis(μ-4-amino-3,5-dimethyl-4H-1,2,4-triazole-κ
(2)
N
(1):N
(2))bis(dibromidozinc) |
title_short | Bis(μ-4-amino-3,5-dimethyl-4H-1,2,4-triazole-κ
(2)
N
(1):N
(2))bis(dibromidozinc) |
title_sort | bis(μ-4-amino-3,5-dimethyl-4h-1,2,4-triazole-κ
(2)
n
(1):n
(2))bis(dibromidozinc) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212254/ https://www.ncbi.nlm.nih.gov/pubmed/22090911 http://dx.doi.org/10.1107/S1600536811028789 |
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