Poly[bis­[μ-1,4-bis­(imidazol-1-ylmeth­yl)benzene]­dichloridomanganese(II)]

In the crystal structure of the title compound, [MnCl(2)(C(14)H(14)N(4))(2)](n), the Mn(II) atom, lying on an inversion center, is coordinated by four N atoms from four 1,4-bis­(imidazol-1-ylmeth­yl)benzene (bimb) ligands and two Cl(−) anions in a distorted octa­hedral geometry. The bimb ligands bri...

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Autores principales: Mei, Chong-Zhen, Shan, Wen-Wen, Li, Kai-Hui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212256/
https://www.ncbi.nlm.nih.gov/pubmed/22090913
http://dx.doi.org/10.1107/S1600536811029485
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author Mei, Chong-Zhen
Shan, Wen-Wen
Li, Kai-Hui
author_facet Mei, Chong-Zhen
Shan, Wen-Wen
Li, Kai-Hui
author_sort Mei, Chong-Zhen
collection PubMed
description In the crystal structure of the title compound, [MnCl(2)(C(14)H(14)N(4))(2)](n), the Mn(II) atom, lying on an inversion center, is coordinated by four N atoms from four 1,4-bis­(imidazol-1-ylmeth­yl)benzene (bimb) ligands and two Cl(−) anions in a distorted octa­hedral geometry. The bimb ligands bridge the Mn(II) atoms, forming a two-dimensional polymeric complex, which is composed of a 52-membered [Mn(4)(bimb)(4)] ring with distances of 7.7812 (2) and 27.4731 (9) Å between opposite metal atoms. Weak C—H⋯π inter­actions are present in the crystal structure.
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spelling pubmed-32122562011-11-16 Poly[bis­[μ-1,4-bis­(imidazol-1-ylmeth­yl)benzene]­dichloridomanganese(II)] Mei, Chong-Zhen Shan, Wen-Wen Li, Kai-Hui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [MnCl(2)(C(14)H(14)N(4))(2)](n), the Mn(II) atom, lying on an inversion center, is coordinated by four N atoms from four 1,4-bis­(imidazol-1-ylmeth­yl)benzene (bimb) ligands and two Cl(−) anions in a distorted octa­hedral geometry. The bimb ligands bridge the Mn(II) atoms, forming a two-dimensional polymeric complex, which is composed of a 52-membered [Mn(4)(bimb)(4)] ring with distances of 7.7812 (2) and 27.4731 (9) Å between opposite metal atoms. Weak C—H⋯π inter­actions are present in the crystal structure. International Union of Crystallography 2011-07-30 /pmc/articles/PMC3212256/ /pubmed/22090913 http://dx.doi.org/10.1107/S1600536811029485 Text en © Mei et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mei, Chong-Zhen
Shan, Wen-Wen
Li, Kai-Hui
Poly[bis­[μ-1,4-bis­(imidazol-1-ylmeth­yl)benzene]­dichloridomanganese(II)]
title Poly[bis­[μ-1,4-bis­(imidazol-1-ylmeth­yl)benzene]­dichloridomanganese(II)]
title_full Poly[bis­[μ-1,4-bis­(imidazol-1-ylmeth­yl)benzene]­dichloridomanganese(II)]
title_fullStr Poly[bis­[μ-1,4-bis­(imidazol-1-ylmeth­yl)benzene]­dichloridomanganese(II)]
title_full_unstemmed Poly[bis­[μ-1,4-bis­(imidazol-1-ylmeth­yl)benzene]­dichloridomanganese(II)]
title_short Poly[bis­[μ-1,4-bis­(imidazol-1-ylmeth­yl)benzene]­dichloridomanganese(II)]
title_sort poly[bis­[μ-1,4-bis­(imidazol-1-ylmeth­yl)benzene]­dichloridomanganese(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212256/
https://www.ncbi.nlm.nih.gov/pubmed/22090913
http://dx.doi.org/10.1107/S1600536811029485
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